Abstract
Exocyclic nitrones smoothly participate in intramolecular cycloaddition reactions to provide bridged and fused polycarbocycles. The exploitation of this methodology in the total syntheses of the sesquiterpenes (±)-7,12-secoishwaran-12-ol (44), (±)-hirsutene (56), (±)-coriolin (68) is also presented.
Original language | English (US) |
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Pages (from-to) | 3479-3495 |
Number of pages | 17 |
Journal | Tetrahedron |
Volume | 41 |
Issue number | 17 |
DOIs | |
State | Published - 1985 |
All Science Journal Classification (ASJC) codes
- Biochemistry
- Drug Discovery
- Organic Chemistry