TY - JOUR
T1 - Investigating the effects of cation electrophilicity, solvent, and temperature on the N-nitrosoamide-mediated polymerization of styrene
AU - Darbeau, Ron W.
AU - Ramelow, Ulku
AU - Delaney, Mark S.
AU - Guillory, Melanie
PY - 2006/8
Y1 - 2006/8
N2 - Styrene was polymerized via thermolyses of N-4-R-benzyl-N-nitrosoamides in heptane, 1-chloroheptane, ethylene dichloride, and DMSO at various temperatures and the glass transition temperatures and MWs obtained. The data show that the polymer yield depends upon solvent, the 4-R-substituent, and temperature. In contrast, both the glass transition temperatures and the MW are insensitive to these factors.
AB - Styrene was polymerized via thermolyses of N-4-R-benzyl-N-nitrosoamides in heptane, 1-chloroheptane, ethylene dichloride, and DMSO at various temperatures and the glass transition temperatures and MWs obtained. The data show that the polymer yield depends upon solvent, the 4-R-substituent, and temperature. In contrast, both the glass transition temperatures and the MW are insensitive to these factors.
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U2 - 10.2174/157017806778559482
DO - 10.2174/157017806778559482
M3 - Article
AN - SCOPUS:33750064250
SN - 1570-1786
VL - 3
SP - 585
EP - 590
JO - Letters in Organic Chemistry
JF - Letters in Organic Chemistry
IS - 8
ER -