Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments

Jennifer S. Zigmond; Kevin A. Pollack; Sarah Smedley; Jeffery E. Raymond; Lauren A. Link; Adriana Pavía-Sanders; Michael A. Hickner; Karen L. Wooley

doi:10.1002/pola.27800

Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments

Jennifer S. Zigmond, Kevin A. Pollack, Sarah Smedley, Jeffery E. Raymond, Lauren A. Link, Adriana Pavía-Sanders, Michael A. Hickner, Karen L. Wooley

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

An array of films composed of a third-generation hyperbranched fluoropolymer crosslinked with poly(ethylene glycol) is generated and tested as an anti-icing coating. Through variation of the hydrophilic:hydrophobic component ratios and drop-casting solvent, significant reductions in the water melting transition temperatures (-5 and -27 C for free and bound water, respectively) are achieved. The novel application of this system displays the expansion and diversity of a well-established coating that demonstrates unique water confinement and sequestration behaviors with the ability to reorganize at the surface.

Original language	English (US)
Pages (from-to)	238-244
Number of pages	7
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	54
Issue number	2
DOIs	https://doi.org/10.1002/pola.27800
State	Published - Jan 15 2016

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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title = "Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments",

abstract = "An array of films composed of a third-generation hyperbranched fluoropolymer crosslinked with poly(ethylene glycol) is generated and tested as an anti-icing coating. Through variation of the hydrophilic:hydrophobic component ratios and drop-casting solvent, significant reductions in the water melting transition temperatures (-5 and -27 C for free and bound water, respectively) are achieved. The novel application of this system displays the expansion and diversity of a well-established coating that demonstrates unique water confinement and sequestration behaviors with the ability to reorganize at the surface.",

author = "Zigmond, \{Jennifer S.\} and Pollack, \{Kevin A.\} and Sarah Smedley and Raymond, \{Jeffery E.\} and Link, \{Lauren A.\} and Adriana Pav{\'i}a-Sanders and Hickner, \{Michael A.\} and Wooley, \{Karen L.\}",

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T1 - Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments

AU - Zigmond, Jennifer S.

AU - Pollack, Kevin A.

AU - Smedley, Sarah

AU - Raymond, Jeffery E.

AU - Link, Lauren A.

AU - Pavía-Sanders, Adriana

AU - Hickner, Michael A.

AU - Wooley, Karen L.

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Y1 - 2016/1/15

N2 - An array of films composed of a third-generation hyperbranched fluoropolymer crosslinked with poly(ethylene glycol) is generated and tested as an anti-icing coating. Through variation of the hydrophilic:hydrophobic component ratios and drop-casting solvent, significant reductions in the water melting transition temperatures (-5 and -27 C for free and bound water, respectively) are achieved. The novel application of this system displays the expansion and diversity of a well-established coating that demonstrates unique water confinement and sequestration behaviors with the ability to reorganize at the surface.

AB - An array of films composed of a third-generation hyperbranched fluoropolymer crosslinked with poly(ethylene glycol) is generated and tested as an anti-icing coating. Through variation of the hydrophilic:hydrophobic component ratios and drop-casting solvent, significant reductions in the water melting transition temperatures (-5 and -27 C for free and bound water, respectively) are achieved. The novel application of this system displays the expansion and diversity of a well-established coating that demonstrates unique water confinement and sequestration behaviors with the ability to reorganize at the surface.

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Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti-icing coatings for extreme environments

Abstract

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