Investigation of the spectroscopic properties of highly transparent Yb:(Y0.97Zr0.03)2O3 ceramic

Xiaorui Hou; Shengming Zhou; Wenjie Li; Yukun Li; Hui Lin; Hao Teng; Tingting Jia

doi:10.1016/j.optmat.2010.05.015

Investigation of the spectroscopic properties of highly transparent Yb:(Y_0.97Zr_0.03)₂O₃ ceramic

Xiaorui Hou, Shengming Zhou, Wenjie Li, Yukun Li, Hui Lin, Hao Teng, Tingting Jia

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

(Y_0.97-xZr_0.03Yb_x) ₂O₃(x = 0-0.15) transparent ceramics were fabricated by solid-state reaction. As ZrO₂ was introduced as additive, the transmittance of yttria ceramic was improved greatly. The optical measurements such as absorption, fluorescence spectrum and lifetime of Yb³⁺ ion were carried out at room temperature. The intensities of the absorption peaks (904 and 973 nm) increase linearly with Yb³⁺ ion concentration. The absorption cross-section at 973 nm and stimulated emission cross-section at 1032 nm are calculated to be 1.175 × 10^-20 and 1.767 × 10^-20 cm², respectively. The lifetime of 5.0 at.% Yb:Y₂O₃ ceramic is measured to be 0.93 ms. According to the emission spectra and measured lifetime, the optimum doping concentration of Yb³⁺ ion in Y₂O₃ transparent ceramic is in the range of 5.0-8.0 at.%. Meanwhile the up-conversion luminescence is also investigated.

Original language	English (US)
Pages (from-to)	1435-1440
Number of pages	6
Journal	Optical Materials
Volume	32
Issue number	11
DOIs	https://doi.org/10.1016/j.optmat.2010.05.015
State	Published - Sep 2010

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Electrical and Electronic Engineering

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title = "Investigation of the spectroscopic properties of highly transparent Yb:(Y0.97Zr0.03)2O3 ceramic",

abstract = "(Y0.97-xZr0.03Ybx) 2O3(x = 0-0.15) transparent ceramics were fabricated by solid-state reaction. As ZrO2 was introduced as additive, the transmittance of yttria ceramic was improved greatly. The optical measurements such as absorption, fluorescence spectrum and lifetime of Yb3+ ion were carried out at room temperature. The intensities of the absorption peaks (904 and 973 nm) increase linearly with Yb3+ ion concentration. The absorption cross-section at 973 nm and stimulated emission cross-section at 1032 nm are calculated to be 1.175 × 10-20 and 1.767 × 10-20 cm2, respectively. The lifetime of 5.0 at.% Yb:Y2O3 ceramic is measured to be 0.93 ms. According to the emission spectra and measured lifetime, the optimum doping concentration of Yb3+ ion in Y2O3 transparent ceramic is in the range of 5.0-8.0 at.%. Meanwhile the up-conversion luminescence is also investigated.",

author = "Xiaorui Hou and Shengming Zhou and Wenjie Li and Yukun Li and Hui Lin and Hao Teng and Tingting Jia",

note = "Funding Information: This work is supported by National Natural Science Foundation of China (No. 60676004 ).",

year = "2010",

month = sep,

doi = "10.1016/j.optmat.2010.05.015",

language = "English (US)",

volume = "32",

pages = "1435--1440",

journal = "Optical Materials",

issn = "0925-3467",

publisher = "Elsevier B.V.",

number = "11",

}

TY - JOUR

T1 - Investigation of the spectroscopic properties of highly transparent Yb:(Y0.97Zr0.03)2O3 ceramic

AU - Hou, Xiaorui

AU - Zhou, Shengming

AU - Li, Wenjie

AU - Li, Yukun

AU - Lin, Hui

AU - Teng, Hao

AU - Jia, Tingting

N1 - Funding Information: This work is supported by National Natural Science Foundation of China (No. 60676004 ).

PY - 2010/9

Y1 - 2010/9

N2 - (Y0.97-xZr0.03Ybx) 2O3(x = 0-0.15) transparent ceramics were fabricated by solid-state reaction. As ZrO2 was introduced as additive, the transmittance of yttria ceramic was improved greatly. The optical measurements such as absorption, fluorescence spectrum and lifetime of Yb3+ ion were carried out at room temperature. The intensities of the absorption peaks (904 and 973 nm) increase linearly with Yb3+ ion concentration. The absorption cross-section at 973 nm and stimulated emission cross-section at 1032 nm are calculated to be 1.175 × 10-20 and 1.767 × 10-20 cm2, respectively. The lifetime of 5.0 at.% Yb:Y2O3 ceramic is measured to be 0.93 ms. According to the emission spectra and measured lifetime, the optimum doping concentration of Yb3+ ion in Y2O3 transparent ceramic is in the range of 5.0-8.0 at.%. Meanwhile the up-conversion luminescence is also investigated.

AB - (Y0.97-xZr0.03Ybx) 2O3(x = 0-0.15) transparent ceramics were fabricated by solid-state reaction. As ZrO2 was introduced as additive, the transmittance of yttria ceramic was improved greatly. The optical measurements such as absorption, fluorescence spectrum and lifetime of Yb3+ ion were carried out at room temperature. The intensities of the absorption peaks (904 and 973 nm) increase linearly with Yb3+ ion concentration. The absorption cross-section at 973 nm and stimulated emission cross-section at 1032 nm are calculated to be 1.175 × 10-20 and 1.767 × 10-20 cm2, respectively. The lifetime of 5.0 at.% Yb:Y2O3 ceramic is measured to be 0.93 ms. According to the emission spectra and measured lifetime, the optimum doping concentration of Yb3+ ion in Y2O3 transparent ceramic is in the range of 5.0-8.0 at.%. Meanwhile the up-conversion luminescence is also investigated.

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JO - Optical Materials

JF - Optical Materials

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ER -

Investigation of the spectroscopic properties of highly transparent Yb:(Y_0.97Zr_0.03)₂O₃ ceramic

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