Iodine-Doped Poly(ethylenepyrrolediyl) Derivatives: A New Class of Nonconjugated Conducting Polymers

Zhaozhong Jiang; Ayusman Sen

doi:10.1021/ma00028a057

Iodine-Doped Poly(ethylenepyrrolediyl) Derivatives: A New Class of Nonconjugated Conducting Polymers

Zhaozhong Jiang, Ayusman Sen

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Poly(ethylenepyrrolediyl) derivatives of the following type (R = n-butyl, 1; C₆H₅, 2; p-CH₃-OC₆H₄, 3) were found to become electronic conductors upon doping with iodine. The conductivity of the iodine-doped polymers was in the range of 5 × 10^-5−2 × 10^-3 Ω^-1 cm^-1. The doped polymers were stable to moisture and oxygen for at least 1 year. The strength and flexibility of the polymers could be improved by cross-linking, although the conductivity was lowered a result.

Original language	English (US)
Pages (from-to)	880-882
Number of pages	3
Journal	Macromolecules
Volume	25
Issue number	2
DOIs	https://doi.org/10.1021/ma00028a057
State	Published - Mar 1 1992

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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title = "Iodine-Doped Poly(ethylenepyrrolediyl) Derivatives: A New Class of Nonconjugated Conducting Polymers",

abstract = "Poly(ethylenepyrrolediyl) derivatives of the following type (R = n-butyl, 1; C6H5, 2; p-CH3-OC6H4, 3) were found to become electronic conductors upon doping with iodine. The conductivity of the iodine-doped polymers was in the range of 5 × 10-5−2 × 10-3 Ω-1 cm-1. The doped polymers were stable to moisture and oxygen for at least 1 year. The strength and flexibility of the polymers could be improved by cross-linking, although the conductivity was lowered a result.",

author = "Zhaozhong Jiang and Ayusman Sen",

year = "1992",

month = mar,

day = "1",

doi = "10.1021/ma00028a057",

language = "English (US)",

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journal = "Macromolecules",

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T1 - Iodine-Doped Poly(ethylenepyrrolediyl) Derivatives

T2 - A New Class of Nonconjugated Conducting Polymers

AU - Jiang, Zhaozhong

AU - Sen, Ayusman

PY - 1992/3/1

Y1 - 1992/3/1

N2 - Poly(ethylenepyrrolediyl) derivatives of the following type (R = n-butyl, 1; C6H5, 2; p-CH3-OC6H4, 3) were found to become electronic conductors upon doping with iodine. The conductivity of the iodine-doped polymers was in the range of 5 × 10-5−2 × 10-3 Ω-1 cm-1. The doped polymers were stable to moisture and oxygen for at least 1 year. The strength and flexibility of the polymers could be improved by cross-linking, although the conductivity was lowered a result.

AB - Poly(ethylenepyrrolediyl) derivatives of the following type (R = n-butyl, 1; C6H5, 2; p-CH3-OC6H4, 3) were found to become electronic conductors upon doping with iodine. The conductivity of the iodine-doped polymers was in the range of 5 × 10-5−2 × 10-3 Ω-1 cm-1. The doped polymers were stable to moisture and oxygen for at least 1 year. The strength and flexibility of the polymers could be improved by cross-linking, although the conductivity was lowered a result.

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JF - Macromolecules

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ER -

Iodine-Doped Poly(ethylenepyrrolediyl) Derivatives: A New Class of Nonconjugated Conducting Polymers

Abstract

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