Iron-catalysed propylene epoxidation by nitrous oxide: Dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

Xiaoxing Wang; Qinghong Zhang; Qian Guo; Yinchuan Lou; Lüjuan Yang; Ye Wang

doi:10.1039/b402839b

Iron-catalysed propylene epoxidation by nitrous oxide: Dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

Xiaoxing Wang
, Qinghong Zhang
, Qian Guo
, Yinchuan Lou
, Lüjuan Yang
, Ye Wang

EMS Energy Institute

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

A dramatic shift of allylic oxidation to epoxidation has been observed during the oxidation of propylene by N₂O when the FeO_x/SBA-15 catalyst is modified with alkali metal salts, and the roles of alkali metal salts are to suppress the reactivity of lattice oxygen and to induce an iron coordination structure effective for epoxidation with N₂O.

Original language	English (US)
Pages (from-to)	1396-1397
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	12
DOIs	https://doi.org/10.1039/b402839b
State	Published - 2004

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b402839b

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title = "Iron-catalysed propylene epoxidation by nitrous oxide: Dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts",

abstract = "A dramatic shift of allylic oxidation to epoxidation has been observed during the oxidation of propylene by N2O when the FeOx/SBA-15 catalyst is modified with alkali metal salts, and the roles of alkali metal salts are to suppress the reactivity of lattice oxygen and to induce an iron coordination structure effective for epoxidation with N2O.",

author = "Xiaoxing Wang and Qinghong Zhang and Qian Guo and Yinchuan Lou and L{\"u}juan Yang and Ye Wang",

year = "2004",

doi = "10.1039/b402839b",

language = "English (US)",

volume = "4",

pages = "1396--1397",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "12",

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TY - JOUR

T1 - Iron-catalysed propylene epoxidation by nitrous oxide

T2 - Dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

AU - Wang, Xiaoxing

AU - Zhang, Qinghong

AU - Guo, Qian

AU - Lou, Yinchuan

AU - Yang, Lüjuan

AU - Wang, Ye

PY - 2004

Y1 - 2004

N2 - A dramatic shift of allylic oxidation to epoxidation has been observed during the oxidation of propylene by N2O when the FeOx/SBA-15 catalyst is modified with alkali metal salts, and the roles of alkali metal salts are to suppress the reactivity of lattice oxygen and to induce an iron coordination structure effective for epoxidation with N2O.

AB - A dramatic shift of allylic oxidation to epoxidation has been observed during the oxidation of propylene by N2O when the FeOx/SBA-15 catalyst is modified with alkali metal salts, and the roles of alkali metal salts are to suppress the reactivity of lattice oxygen and to induce an iron coordination structure effective for epoxidation with N2O.

UR - https://www.scopus.com/pages/publications/3142752720

UR - https://www.scopus.com/pages/publications/3142752720#tab=citedBy

U2 - 10.1039/b402839b

DO - 10.1039/b402839b

M3 - Article

AN - SCOPUS:3142752720

SN - 1359-7345

VL - 4

SP - 1396

EP - 1397

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Iron-catalysed propylene epoxidation by nitrous oxide: Dramatic shift of allylic oxidation to epoxidation by the modification with alkali metal salts

Abstract

All Science Journal Classification (ASJC) codes

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