Langmuir-Adam trough studies of hydrophobicity, hydrophilicity, and amphilicity in small-molecule and high-polymeric phosphazenes

Lawrence L. Mack; Richard J. Fitzpatrick; Harry R. Allcock

doi:10.1021/la950453v

Langmuir-Adam trough studies of hydrophobicity, hydrophilicity, and amphilicity in small-molecule and high-polymeric phosphazenes

Lawrence L. Mack, Richard J. Fitzpatrick, Harry R. Allcock

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11 Scopus citations

Abstract

Langmuir-Adam trough studies have been carried out to study the behavior of seven cyclic and linear short-chain small-molecule phosphazenes and four high polymers at air-water interfaces. The small-molecule compounds are models for a variety of phosphazene high polymers. The influence of phenoxy, 1,2-benzenedioxy, OCH₂CF₃, NH₂, NEt₂, NBu₂, and OCH₂CH₂CH₂CH₂OCH₃ side groups was studied. The air-water interface behavior of the small molecules depended on (a) the cyclic or linear skeletal structure and (b) the types of side groups linked to the ring or chain. The utilization of these results for understanding the behavior of phosphazene high polymers at air-water interfaces is discussed.

Original language	English (US)
Pages (from-to)	2123-2132
Number of pages	10
Journal	Langmuir
Volume	13
Issue number	7
DOIs	https://doi.org/10.1021/la950453v
State	Published - Apr 2 1997

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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abstract = "Langmuir-Adam trough studies have been carried out to study the behavior of seven cyclic and linear short-chain small-molecule phosphazenes and four high polymers at air-water interfaces. The small-molecule compounds are models for a variety of phosphazene high polymers. The influence of phenoxy, 1,2-benzenedioxy, OCH2CF3, NH2, NEt2, NBu2, and OCH2CH2CH2CH2OCH3 side groups was studied. The air-water interface behavior of the small molecules depended on (a) the cyclic or linear skeletal structure and (b) the types of side groups linked to the ring or chain. The utilization of these results for understanding the behavior of phosphazene high polymers at air-water interfaces is discussed.",

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AU - Fitzpatrick, Richard J.

AU - Allcock, Harry R.

PY - 1997/4/2

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N2 - Langmuir-Adam trough studies have been carried out to study the behavior of seven cyclic and linear short-chain small-molecule phosphazenes and four high polymers at air-water interfaces. The small-molecule compounds are models for a variety of phosphazene high polymers. The influence of phenoxy, 1,2-benzenedioxy, OCH2CF3, NH2, NEt2, NBu2, and OCH2CH2CH2CH2OCH3 side groups was studied. The air-water interface behavior of the small molecules depended on (a) the cyclic or linear skeletal structure and (b) the types of side groups linked to the ring or chain. The utilization of these results for understanding the behavior of phosphazene high polymers at air-water interfaces is discussed.

AB - Langmuir-Adam trough studies have been carried out to study the behavior of seven cyclic and linear short-chain small-molecule phosphazenes and four high polymers at air-water interfaces. The small-molecule compounds are models for a variety of phosphazene high polymers. The influence of phenoxy, 1,2-benzenedioxy, OCH2CF3, NH2, NEt2, NBu2, and OCH2CH2CH2CH2OCH3 side groups was studied. The air-water interface behavior of the small molecules depended on (a) the cyclic or linear skeletal structure and (b) the types of side groups linked to the ring or chain. The utilization of these results for understanding the behavior of phosphazene high polymers at air-water interfaces is discussed.

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Langmuir-Adam trough studies of hydrophobicity, hydrophilicity, and amphilicity in small-molecule and high-polymeric phosphazenes

Abstract

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