Liquid-phase decomposition mechanism of triaminoguanidinium azotetrazolate

Neeraj R. Kumbhakarna; Kaushal J. Shah; Arindrajit Chowdhury; Stefan Thynell

Liquid-phase decomposition mechanism of triaminoguanidinium azotetrazolate

Neeraj R. Kumbhakarna, Kaushal J. Shah, Arindrajit Chowdhury, Stefan Thynell

Research output: Contribution to conference › Paper › peer-review

Abstract

The objective of this work is to analyze the decomposition of triaminoguanidinium azotetrazolate (TAGzT) in the liquid phase by using a combined experimental and computational approach. The experimental part involves the use of Fourier transform infrared (FTIR) spectroscopy and Time-of-flight mass spectrometry (ToFMS) analysis of TAGzT decomposition. N₂, NH₃, HCN, N₂H₄, and the 3-azido-1,2,4-triazol-4-ide anion were identified as products of decomposition. The computational approach is based on using quantum mechanics for confirming the identity of the species observed in experiments and for identifying elementary chemical reactions that form these species.

Original language	English (US)
State	Published - Jan 1 2015
Event	10th Asia-Pacific Conference on Combustion, ASPACC 2015 - Beijing, China Duration: Jul 19 2015 → Jul 22 2015

Other

Other	10th Asia-Pacific Conference on Combustion, ASPACC 2015
Country/Territory	China
City	Beijing
Period	7/19/15 → 7/22/15

All Science Journal Classification (ASJC) codes

Energy Engineering and Power Technology
Fuel Technology
General Chemical Engineering
Condensed Matter Physics

Cite this

@conference{cf751fdf72cb4dcc8a9e869624f551d7,

title = "Liquid-phase decomposition mechanism of triaminoguanidinium azotetrazolate",

abstract = "The objective of this work is to analyze the decomposition of triaminoguanidinium azotetrazolate (TAGzT) in the liquid phase by using a combined experimental and computational approach. The experimental part involves the use of Fourier transform infrared (FTIR) spectroscopy and Time-of-flight mass spectrometry (ToFMS) analysis of TAGzT decomposition. N2, NH3, HCN, N2H4, and the 3-azido-1,2,4-triazol-4-ide anion were identified as products of decomposition. The computational approach is based on using quantum mechanics for confirming the identity of the species observed in experiments and for identifying elementary chemical reactions that form these species.",

author = "Kumbhakarna, {Neeraj R.} and Shah, {Kaushal J.} and Arindrajit Chowdhury and Stefan Thynell",

year = "2015",

month = jan,

day = "1",

language = "English (US)",

note = "10th Asia-Pacific Conference on Combustion, ASPACC 2015 ; Conference date: 19-07-2015 Through 22-07-2015",

}

TY - CONF

T1 - Liquid-phase decomposition mechanism of triaminoguanidinium azotetrazolate

AU - Kumbhakarna, Neeraj R.

AU - Shah, Kaushal J.

AU - Chowdhury, Arindrajit

AU - Thynell, Stefan

PY - 2015/1/1

Y1 - 2015/1/1

N2 - The objective of this work is to analyze the decomposition of triaminoguanidinium azotetrazolate (TAGzT) in the liquid phase by using a combined experimental and computational approach. The experimental part involves the use of Fourier transform infrared (FTIR) spectroscopy and Time-of-flight mass spectrometry (ToFMS) analysis of TAGzT decomposition. N2, NH3, HCN, N2H4, and the 3-azido-1,2,4-triazol-4-ide anion were identified as products of decomposition. The computational approach is based on using quantum mechanics for confirming the identity of the species observed in experiments and for identifying elementary chemical reactions that form these species.

AB - The objective of this work is to analyze the decomposition of triaminoguanidinium azotetrazolate (TAGzT) in the liquid phase by using a combined experimental and computational approach. The experimental part involves the use of Fourier transform infrared (FTIR) spectroscopy and Time-of-flight mass spectrometry (ToFMS) analysis of TAGzT decomposition. N2, NH3, HCN, N2H4, and the 3-azido-1,2,4-triazol-4-ide anion were identified as products of decomposition. The computational approach is based on using quantum mechanics for confirming the identity of the species observed in experiments and for identifying elementary chemical reactions that form these species.

UR - http://www.scopus.com/inward/record.url?scp=84947277874&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84947277874&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:84947277874

T2 - 10th Asia-Pacific Conference on Combustion, ASPACC 2015

Y2 - 19 July 2015 through 22 July 2015

ER -

Liquid-phase decomposition mechanism of triaminoguanidinium azotetrazolate

Abstract

Other

All Science Journal Classification (ASJC) codes

Other files and links

Fingerprint

Cite this