Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

N. I. Kovtyukhova; V. M. Belousov; S. V. Mikhalovskii; L. D. Kvacheva; Yu N. Novikov; M. E. Vol'pin

doi:10.1007/BF01167752

Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

N. I. Kovtyukhova, V. M. Belousov, S. V. Mikhalovskii, L. D. Kvacheva, Yu N. Novikov, M. E. Vol'pin

Chemistry

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Abstract

1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl₅. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

Original language	English (US)
Pages (from-to)	16-20
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	32
Issue number	1
DOIs	https://doi.org/10.1007/BF01167752
State	Published - Jan 1983

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1007/BF01167752

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@article{344fe96fbd3740929f8e5d7ce40e3544,

title = "Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides",

abstract = "1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.",

author = "Kovtyukhova, {N. I.} and Belousov, {V. M.} and Mikhalovskii, {S. V.} and Kvacheva, {L. D.} and Novikov, {Yu N.} and Vol'pin, {M. E.}",

year = "1983",

month = jan,

doi = "10.1007/BF01167752",

language = "English (US)",

volume = "32",

pages = "16--20",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "1",

}

Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides. / Kovtyukhova, N. I.; Belousov, V. M.; Mikhalovskii, S. V. et al.
In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 32, No. 1, 01.1983, p. 16-20.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

AU - Kovtyukhova, N. I.

AU - Belousov, V. M.

AU - Mikhalovskii, S. V.

AU - Kvacheva, L. D.

AU - Novikov, Yu N.

AU - Vol'pin, M. E.

PY - 1983/1

Y1 - 1983/1

N2 - 1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

AB - 1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

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U2 - 10.1007/BF01167752

DO - 10.1007/BF01167752

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VL - 32

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 1

ER -

Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

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