Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

N. I. Kovtyukhova; V. M. Belousov; S. V. Mikhalovskii; L. D. Kvacheva; Yu N. Novikov; M. E. Vol'pin

doi:10.1007/BF01167752

Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

N. I. Kovtyukhova, V. M. Belousov, S. V. Mikhalovskii, L. D. Kvacheva, Yu N. Novikov, M. E. Vol'pin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl₅. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

Original language	English (US)
Pages (from-to)	16-20
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	32
Issue number	1
DOIs	https://doi.org/10.1007/BF01167752
State	Published - Jan 1983

All Science Journal Classification (ASJC) codes

General Chemistry

Access to Document

10.1007/BF01167752

Cite this

@article{344fe96fbd3740929f8e5d7ce40e3544,

title = "Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides",

abstract = "1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.",

author = "Kovtyukhova, \{N. I.\} and Belousov, \{V. M.\} and Mikhalovskii, \{S. V.\} and Kvacheva, \{L. D.\} and Novikov, \{Yu N.\} and Vol'pin, \{M. E.\}",

year = "1983",

month = jan,

doi = "10.1007/BF01167752",

language = "English (US)",

volume = "32",

pages = "16--20",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "1",

}

Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides. / Kovtyukhova, N. I.; Belousov, V. M.; Mikhalovskii, S. V. et al.
In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 32, No. 1, 01.1983, p. 16-20.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

AU - Kovtyukhova, N. I.

AU - Belousov, V. M.

AU - Mikhalovskii, S. V.

AU - Kvacheva, L. D.

AU - Novikov, Yu N.

AU - Vol'pin, M. E.

PY - 1983/1

Y1 - 1983/1

N2 - 1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

AB - 1. Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5. 2. On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

UR - https://www.scopus.com/pages/publications/34250152795

UR - https://www.scopus.com/inward/citedby.url?scp=34250152795&partnerID=8YFLogxK

U2 - 10.1007/BF01167752

DO - 10.1007/BF01167752

M3 - Article

AN - SCOPUS:34250152795

SN - 0568-5230

VL - 32

SP - 16

EP - 20

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 1

ER -

Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this