MEAN MOLAL STOICHIOMETRIC ACTIVITY COEFFICIENTS OF ALKALI HALIDES AND RELATED ELECTROLYTES IN HYDROTHERMAL SOLUTIONS.

S. A. Wood; D. A. Crerar; Susan Louise Brantley; M. Borcsik

doi:10.2475/ajs.284.6.668

MEAN MOLAL STOICHIOMETRIC ACTIVITY COEFFICIENTS OF ALKALI HALIDES AND RELATED ELECTROLYTES IN HYDROTHERMAL SOLUTIONS.

S. A. Wood, D. A. Crerar, Susan Louise Brantley, M. Borcsik

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

The mean molal stoichiometric activity coefficients have been measured for NaCl at 325 and 350 degree C and for KCl and CaCl//2 from 200 to 350 degree C using the static vapor pressure method. Differential vapor pressure measurements made using a strain-gauge transducer proved to be rapid and accurate. A simple method is presented that factors the activity coefficient into three parts corresponding to long-range electrostatic ion-ion interactions, hydration, and association; this reproduces experimental values with reasonable accuracy. Refs.

Original language	English (US)
Pages (from-to)	668-705
Number of pages	38
Journal	American Journal of Science
Volume	284
Issue number	6
DOIs	https://doi.org/10.2475/ajs.284.6.668
State	Published - 1984

All Science Journal Classification (ASJC) codes

General Earth and Planetary Sciences

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abstract = "The mean molal stoichiometric activity coefficients have been measured for NaCl at 325 and 350 degree C and for KCl and CaCl//2 from 200 to 350 degree C using the static vapor pressure method. Differential vapor pressure measurements made using a strain-gauge transducer proved to be rapid and accurate. A simple method is presented that factors the activity coefficient into three parts corresponding to long-range electrostatic ion-ion interactions, hydration, and association; this reproduces experimental values with reasonable accuracy. Refs.",

author = "Wood, {S. A.} and Crerar, {D. A.} and Brantley, {Susan Louise} and M. Borcsik",

year = "1984",

doi = "10.2475/ajs.284.6.668",

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AU - Crerar, D. A.

AU - Brantley, Susan Louise

AU - Borcsik, M.

PY - 1984

Y1 - 1984

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AB - The mean molal stoichiometric activity coefficients have been measured for NaCl at 325 and 350 degree C and for KCl and CaCl//2 from 200 to 350 degree C using the static vapor pressure method. Differential vapor pressure measurements made using a strain-gauge transducer proved to be rapid and accurate. A simple method is presented that factors the activity coefficient into three parts corresponding to long-range electrostatic ion-ion interactions, hydration, and association; this reproduces experimental values with reasonable accuracy. Refs.

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MEAN MOLAL STOICHIOMETRIC ACTIVITY COEFFICIENTS OF ALKALI HALIDES AND RELATED ELECTROLYTES IN HYDROTHERMAL SOLUTIONS.

Abstract

All Science Journal Classification (ASJC) codes

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