Mechanism of Reduction of an Aminyl Radical Intermediate in the Radical SAM GTP 3′,8-Cyclase MoaA

Keyphrases

• 5′-deoxyadenosine 20%
• Active Sites 40%
• AUX1 20%
• Cyclase 100%
• Cyclization 20%
• Density Functional Calculations 20%
• Electron Donor 20%
• Electron Paramagnetic Resonance 20%
• Electron Paramagnetic Resonance Spectroscopy 20%
• Electron Transfer 20%
• Enzyme Catalysis 20%
• Exchange Interaction 20%
• Experimental Demonstration 20%
• Large Families 20%
• Mechanistic Insight 20%
• Mechanistic Investigation 20%
• Molybdenum Cofactor Biosynthesis 20%
• Protein Film 20%
• Proton Donor 20%
• Proton-coupled Electron Transfer 20%
• Q-band 20%
• Radical Intermediates 100%
• Radical Reduction 20%
• Reduction Potential 20%
• S-adenosylmethionine 100%
• Spasm 20%
• Twitch 20%
• Voltammogram 20%

Biochemistry, Genetics and Molecular Biology

• Active Site 40%
• Anabolism 20%
• Cyclase 100%
• Deoxyadenosine 20%
• Electron Transport 40%
• Enzyme 40%
• Enzyme Catalysis 20%
• Guanosine Triphosphate 100%
• Molybdenum Cofactor 20%
• S-Adenosyl Methionine 100%

Chemistry

• Catalysis 20%
• Cofactor 20%
• Density Functional Theory 20%
• Donor 20%
• Electron Donor 20%
• Electron Transport 40%
• EPR Spectroscopy 40%
• Exchange Interaction 20%
• Group Transfer Polymerization 40%
• Methionine 100%
• Molybdenum 20%
• Reduction Potential 20%