Abstract
Phosphoranes are formed when halocyclophosphazenes or spiro[arylenedioxycyclophosphazenes] react with ortho dinucleophiles such as catechol and base or o-aminophenol. With the latter reagent, a critical intermediate in the degradation pathway, iminobis[spiro[bis(o-phenyleneoxyamino)phosphorane]], has been isolated. The effects of temperature, solvent, and other nucleophiles on these reactions have been analyzed, and the reaction pathways are discussed.
Original language | English (US) |
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Pages (from-to) | 2831-2837 |
Number of pages | 7 |
Journal | Inorganic chemistry |
Volume | 14 |
Issue number | 11 |
DOIs | |
State | Published - Nov 1 1975 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry