Mechanism of the Reactions between Ortho Dinucleophiles and Cyclophosphazenes

H. R. Allcock; R. L. Kugel; G. Y. Moore

doi:10.1021/ic50153a048

Mechanism of the Reactions between Ortho Dinucleophiles and Cyclophosphazenes

H. R. Allcock
, R. L. Kugel
, G. Y. Moore

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Phosphoranes are formed when halocyclophosphazenes or spiro[arylenedioxycyclophosphazenes] react with ortho dinucleophiles such as catechol and base or o-aminophenol. With the latter reagent, a critical intermediate in the degradation pathway, iminobis[spiro[bis(o-phenyleneoxyamino)phosphorane]], has been isolated. The effects of temperature, solvent, and other nucleophiles on these reactions have been analyzed, and the reaction pathways are discussed.

Original language	English (US)
Pages (from-to)	2831-2837
Number of pages	7
Journal	Inorganic chemistry
Volume	14
Issue number	11
DOIs	https://doi.org/10.1021/ic50153a048
State	Published - Nov 1 1975

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "Phosphoranes are formed when halocyclophosphazenes or spiro[arylenedioxycyclophosphazenes] react with ortho dinucleophiles such as catechol and base or o-aminophenol. With the latter reagent, a critical intermediate in the degradation pathway, iminobis[spiro[bis(o-phenyleneoxyamino)phosphorane]], has been isolated. The effects of temperature, solvent, and other nucleophiles on these reactions have been analyzed, and the reaction pathways are discussed.",

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AU - Allcock, H. R.

AU - Kugel, R. L.

AU - Moore, G. Y.

PY - 1975/11/1

Y1 - 1975/11/1

N2 - Phosphoranes are formed when halocyclophosphazenes or spiro[arylenedioxycyclophosphazenes] react with ortho dinucleophiles such as catechol and base or o-aminophenol. With the latter reagent, a critical intermediate in the degradation pathway, iminobis[spiro[bis(o-phenyleneoxyamino)phosphorane]], has been isolated. The effects of temperature, solvent, and other nucleophiles on these reactions have been analyzed, and the reaction pathways are discussed.

AB - Phosphoranes are formed when halocyclophosphazenes or spiro[arylenedioxycyclophosphazenes] react with ortho dinucleophiles such as catechol and base or o-aminophenol. With the latter reagent, a critical intermediate in the degradation pathway, iminobis[spiro[bis(o-phenyleneoxyamino)phosphorane]], has been isolated. The effects of temperature, solvent, and other nucleophiles on these reactions have been analyzed, and the reaction pathways are discussed.

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UR - https://www.scopus.com/pages/publications/0007450190#tab=citedBy

U2 - 10.1021/ic50153a048

DO - 10.1021/ic50153a048

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JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 11

ER -

Mechanism of the Reactions between Ortho Dinucleophiles and Cyclophosphazenes

Abstract

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