Mechanochemical synthesis of complex zirconium phosphates

M. V. Chaikina; V. A. Sadykov; S. N. Pavlova; G. N. Zabolotnaya; R. I. Maximovskaya; V. V. Kriventsov; D. I. Kochubey; E. B. Burgina; R. Roy; D. K. Agrawal

doi:10.1023/A:1011334125802

Mechanochemical synthesis of complex zirconium phosphates

M. V. Chaikina, V. A. Sadykov, S. N. Pavlova, G. N. Zabolotnaya, R. I. Maximovskaya, V. V. Kriventsov, D. I. Kochubey, E. B. Burgina, R. Roy, D. K. Agrawal

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

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Abstract

Cation- and anion-substituted zirconium phosphates of X_kZr_m(PO₄)_n-yY composition, where X = Na⁺, La³⁺, NH₄⁺, Y = F^-, WO₄^2-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [³¹P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

Original language	English (US)
Pages (from-to)	279-286
Number of pages	8
Journal	Journal of Materials Synthesis and Processing
Volume	8
Issue number	5-6
DOIs	https://doi.org/10.1023/A:1011334125802
State	Published - Nov 2000

All Science Journal Classification (ASJC) codes

General Materials Science

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10.1023/A:1011334125802

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@article{4b7bff05c7fc43f0b0cb7ccfabcaef84,

title = "Mechanochemical synthesis of complex zirconium phosphates",

abstract = "Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.",

author = "Chaikina, {M. V.} and Sadykov, {V. A.} and Pavlova, {S. N.} and Zabolotnaya, {G. N.} and Maximovskaya, {R. I.} and Kriventsov, {V. V.} and Kochubey, {D. I.} and Burgina, {E. B.} and R. Roy and Agrawal, {D. K.}",

note = "Funding Information: This work is in part supported by the Universities of Russia Project No. 3514.",

year = "2000",

month = nov,

doi = "10.1023/A:1011334125802",

language = "English (US)",

volume = "8",

pages = "279--286",

journal = "Journal of Materials Synthesis and Processing",

issn = "1064-7562",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "5-6",

}

TY - JOUR

T1 - Mechanochemical synthesis of complex zirconium phosphates

AU - Chaikina, M. V.

AU - Sadykov, V. A.

AU - Pavlova, S. N.

AU - Zabolotnaya, G. N.

AU - Maximovskaya, R. I.

AU - Kriventsov, V. V.

AU - Kochubey, D. I.

AU - Burgina, E. B.

AU - Roy, R.

AU - Agrawal, D. K.

N1 - Funding Information: This work is in part supported by the Universities of Russia Project No. 3514.

PY - 2000/11

Y1 - 2000/11

N2 - Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

AB - Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

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U2 - 10.1023/A:1011334125802

DO - 10.1023/A:1011334125802

M3 - Article

AN - SCOPUS:0034312077

SN - 1064-7562

VL - 8

SP - 279

EP - 286

JO - Journal of Materials Synthesis and Processing

JF - Journal of Materials Synthesis and Processing

IS - 5-6

ER -

Mechanochemical synthesis of complex zirconium phosphates

Abstract

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