Mechanochemical synthesis of complex zirconium phosphates

M. V. Chaikina, V. A. Sadykov, S. N. Pavlova, G. N. Zabolotnaya, R. I. Maximovskaya, V. V. Kriventsov, D. I. Kochubey, E. B. Burgina, R. Roy, D. K. Agrawal

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Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

Original languageEnglish (US)
Pages (from-to)279-286
Number of pages8
JournalJournal of Materials Synthesis and Processing
Issue number5-6
StatePublished - Nov 2000

All Science Journal Classification (ASJC) codes

  • General Materials Science


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