Mechanochemical synthesis of complex zirconium phosphates

M. V. Chaikina; V. A. Sadykov; S. N. Pavlova; G. N. Zabolotnaya; R. I. Maximovskaya; V. V. Kriventsov; D. I. Kochubey; E. B. Burgina; R. Roy; D. K. Agrawal

doi:10.1023/A:1011334125802

Mechanochemical synthesis of complex zirconium phosphates

M. V. Chaikina
, V. A. Sadykov
, S. N. Pavlova
, G. N. Zabolotnaya
, R. I. Maximovskaya
, V. V. Kriventsov
, D. I. Kochubey
, E. B. Burgina
, R. Roy
, D. K. Agrawal

Materials Research Institute (MRI)

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Cation- and anion-substituted zirconium phosphates of X_kZr_m(PO₄)_n-yY composition, where X = Na⁺, La³⁺, NH₄⁺, Y = F^-, WO₄^2-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [³¹P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

Original language	English (US)
Pages (from-to)	279-286
Number of pages	8
Journal	Journal of Materials Synthesis and Processing
Volume	8
Issue number	5-6
DOIs	https://doi.org/10.1023/A:1011334125802
State	Published - Nov 2000

All Science Journal Classification (ASJC) codes

General Materials Science

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10.1023/A:1011334125802

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@article{4b7bff05c7fc43f0b0cb7ccfabcaef84,

title = "Mechanochemical synthesis of complex zirconium phosphates",

abstract = "Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.",

author = "Chaikina, \{M. V.\} and Sadykov, \{V. A.\} and Pavlova, \{S. N.\} and Zabolotnaya, \{G. N.\} and Maximovskaya, \{R. I.\} and Kriventsov, \{V. V.\} and Kochubey, \{D. I.\} and Burgina, \{E. B.\} and R. Roy and Agrawal, \{D. K.\}",

note = "Funding Information: This work is in part supported by the Universities of Russia Project No. 3514.",

year = "2000",

month = nov,

doi = "10.1023/A:1011334125802",

language = "English (US)",

volume = "8",

pages = "279--286",

journal = "Journal of Materials Synthesis and Processing",

issn = "1064-7562",

publisher = "Springer GmbH \& Co, Auslieferungs-Gesellschaf",

number = "5-6",

}

TY - JOUR

T1 - Mechanochemical synthesis of complex zirconium phosphates

AU - Chaikina, M. V.

AU - Sadykov, V. A.

AU - Pavlova, S. N.

AU - Zabolotnaya, G. N.

AU - Maximovskaya, R. I.

AU - Kriventsov, V. V.

AU - Kochubey, D. I.

AU - Burgina, E. B.

AU - Roy, R.

AU - Agrawal, D. K.

N1 - Funding Information: This work is in part supported by the Universities of Russia Project No. 3514.

PY - 2000/11

Y1 - 2000/11

N2 - Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

AB - Cation- and anion-substituted zirconium phosphates of XkZrm(PO4)n-yY composition, where X = Na+, La3+, NH4+, Y = F-, WO42-, 1/3 < k < 2, 2 < m < 4, 3 < n < 6 were synthesized by the procedure, including mechanical activation of the starting salts mixture followed by annealing at 300-900°C. The interaction between components was studied by XRD, EXAFS, FT-IR, [31P-MAS] NMR. The possibility of synthesizing nonstoichiometric compounds is demonstrated and prospects for application of the mechanochemical method for synthesis of complex zirconium phosphates are outlined.

UR - https://www.scopus.com/pages/publications/0034312077

UR - https://www.scopus.com/pages/publications/0034312077#tab=citedBy

U2 - 10.1023/A:1011334125802

DO - 10.1023/A:1011334125802

M3 - Article

AN - SCOPUS:0034312077

SN - 1064-7562

VL - 8

SP - 279

EP - 286

JO - Journal of Materials Synthesis and Processing

JF - Journal of Materials Synthesis and Processing

IS - 5-6

ER -

Mechanochemical synthesis of complex zirconium phosphates

Abstract

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