Metal-Free Removal of Polymer Chain Ends Using Light

Kaila M. Mattson, Christian W. Pester, Will R. Gutekunst, Andy T. Hsueh, Emre H. Discekici, Yingdong Luo, Bernhard V.K.J. Schmidt, Alaina J. McGrath, Paul G. Clark, Craig J. Hawker

Research output: Contribution to journalArticlepeer-review

36 Scopus citations


A light-mediated method for the facile removal of polymer end groups that are common to controlled radical polymerization techniques is presented. This metal-free strategy is general, being effective for chlorine, bromine, and thiocarbonylthio moieties as well as a number of different polymer families (styrenic, acrylic, and methacrylic). In addition to solution reactions, this process is readily translated to thin films, where light mediation allows the straightforward fabrication of hierarchically patterned polymer brushes.

Original languageEnglish (US)
Pages (from-to)8162-8166
Number of pages5
Issue number21
StatePublished - Nov 8 2016

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry


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