Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide

Man Rong Li; Mark Croft; Peter W. Stephens; Meng Ye; David Vanderbilt; Maria Retuerto; Zheng Deng; Christoph P. Grams; Joachim Hemberger; Joke Hadermann; Wen Min Li; Chang Qing Jin; Felix O. Saouma; Joon I. Jang; Hirofumi Akamatsu; Venkatraman Gopalan; David Walker; Martha Greenblatt

doi:10.1002/adma.201405244

Mn₂FeWO₆: A New Ni₃TeO₆-Type Polar and Magnetic Oxide

Man Rong Li, Mark Croft, Peter W. Stephens, Meng Ye, David Vanderbilt, Maria Retuerto, Zheng Deng, Christoph P. Grams, Joachim Hemberger, Joke Hadermann, Wen Min Li, Chang Qing Jin, Felix O. Saouma, Joon I. Jang, Hirofumi Akamatsu, Venkatraman Gopalan, David Walker, Martha Greenblatt

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Mn²⁺₂Fe²⁺W⁶⁺O₆, a new polar magnetic phase, adopts the corundum-derived Ni₃TeO₆-type structure with large spontaneous polarization (P_S) of 67.8 μC cm^-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

Original language	English (US)
Pages (from-to)	2177-2181
Number of pages	5
Journal	Advanced Materials
Volume	27
Issue number	13
DOIs	https://doi.org/10.1002/adma.201405244
State	Published - Apr 1 2015

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

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Li, M. R., Croft, M., Stephens, P. W., Ye, M., Vanderbilt, D., Retuerto, M., Deng, Z., Grams, C. P., Hemberger, J., Hadermann, J., Li, W. M., Jin, C. Q., Saouma, F. O., Jang, J. I., Akamatsu, H., Gopalan, V., Walker, D., & Greenblatt, M. (2015). Mn₂FeWO₆: A New Ni₃TeO₆-Type Polar and Magnetic Oxide. Advanced Materials, 27(13), 2177-2181. https://doi.org/10.1002/adma.201405244

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title = "Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide",

abstract = "Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (PS) of 67.8 μC cm-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.",

author = "Li, {Man Rong} and Mark Croft and Stephens, {Peter W.} and Meng Ye and David Vanderbilt and Maria Retuerto and Zheng Deng and Grams, {Christoph P.} and Joachim Hemberger and Joke Hadermann and Li, {Wen Min} and Jin, {Chang Qing} and Saouma, {Felix O.} and Jang, {Joon I.} and Hirofumi Akamatsu and Venkatraman Gopalan and David Walker and Martha Greenblatt",

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year = "2015",

month = apr,

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doi = "10.1002/adma.201405244",

language = "English (US)",

volume = "27",

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TY - JOUR

T1 - Mn2FeWO6

T2 - A New Ni3TeO6-Type Polar and Magnetic Oxide

AU - Li, Man Rong

AU - Croft, Mark

AU - Stephens, Peter W.

AU - Ye, Meng

AU - Vanderbilt, David

AU - Retuerto, Maria

AU - Deng, Zheng

AU - Grams, Christoph P.

AU - Hemberger, Joachim

AU - Hadermann, Joke

AU - Li, Wen Min

AU - Jin, Chang Qing

AU - Saouma, Felix O.

AU - Jang, Joon I.

AU - Akamatsu, Hirofumi

AU - Gopalan, Venkatraman

AU - Walker, David

AU - Greenblatt, Martha

PY - 2015/4/1

Y1 - 2015/4/1

N2 - Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (PS) of 67.8 μC cm-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

AB - Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (PS) of 67.8 μC cm-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

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VL - 27

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JO - Advanced Materials

JF - Advanced Materials

IS - 13

ER -

Mn₂FeWO₆: A New Ni₃TeO₆-Type Polar and Magnetic Oxide

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