Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide

Man Rong Li; Mark Croft; Peter W. Stephens; Meng Ye; David Vanderbilt; Maria Retuerto; Zheng Deng; Christoph P. Grams; Joachim Hemberger; Joke Hadermann; Wen Min Li; Chang Qing Jin; Felix O. Saouma; Joon I. Jang; Hirofumi Akamatsu; Venkatraman Gopalan; David Walker; Martha Greenblatt

doi:10.1002/adma.201405244

Mn₂FeWO₆: A New Ni₃TeO₆-Type Polar and Magnetic Oxide

Man Rong Li
, Mark Croft
, Peter W. Stephens
, Meng Ye
, David Vanderbilt
, Maria Retuerto
, Zheng Deng
, Christoph P. Grams
, Joachim Hemberger
, Joke Hadermann
, Wen Min Li
, Chang Qing Jin
, Felix O. Saouma
, Joon I. Jang
, Hirofumi Akamatsu
, Venkatraman Gopalan
, David Walker
, Martha Greenblatt

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Mn²⁺₂Fe²⁺W⁶⁺O₆, a new polar magnetic phase, adopts the corundum-derived Ni₃TeO₆-type structure with large spontaneous polarization (P_S) of 67.8 μC cm^-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

Original language	English (US)
Pages (from-to)	2177-2181
Number of pages	5
Journal	Advanced Materials
Volume	27
Issue number	13
DOIs	https://doi.org/10.1002/adma.201405244
State	Published - Apr 1 2015

All Science Journal Classification (ASJC) codes

General Materials Science
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.201405244

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Li, M. R., Croft, M., Stephens, P. W., Ye, M., Vanderbilt, D., Retuerto, M., Deng, Z., Grams, C. P., Hemberger, J., Hadermann, J., Li, W. M., Jin, C. Q., Saouma, F. O., Jang, J. I., Akamatsu, H., Gopalan, V., Walker, D., & Greenblatt, M. (2015). Mn₂FeWO₆: A New Ni₃TeO₆-Type Polar and Magnetic Oxide. Advanced Materials, 27(13), 2177-2181. https://doi.org/10.1002/adma.201405244

@article{d958070b6f35497399bc73335573fa10,

title = "Mn2FeWO6: A New Ni3TeO6-Type Polar and Magnetic Oxide",

abstract = "Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (PS) of 67.8 μC cm-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.",

author = "Li, \{Man Rong\} and Mark Croft and Stephens, \{Peter W.\} and Meng Ye and David Vanderbilt and Maria Retuerto and Zheng Deng and Grams, \{Christoph P.\} and Joachim Hemberger and Joke Hadermann and Li, \{Wen Min\} and Jin, \{Chang Qing\} and Saouma, \{Felix O.\} and Jang, \{Joon I.\} and Hirofumi Akamatsu and Venkatraman Gopalan and David Walker and Martha Greenblatt",

note = "Publisher Copyright: {\textcopyright} 2015 Wiley-VCH Verlag GmbH \& Co.",

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month = apr,

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doi = "10.1002/adma.201405244",

language = "English (US)",

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TY - JOUR

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T2 - A New Ni3TeO6-Type Polar and Magnetic Oxide

AU - Li, Man Rong

AU - Croft, Mark

AU - Stephens, Peter W.

AU - Ye, Meng

AU - Vanderbilt, David

AU - Retuerto, Maria

AU - Deng, Zheng

AU - Grams, Christoph P.

AU - Hemberger, Joachim

AU - Hadermann, Joke

AU - Li, Wen Min

AU - Jin, Chang Qing

AU - Saouma, Felix O.

AU - Jang, Joon I.

AU - Akamatsu, Hirofumi

AU - Gopalan, Venkatraman

AU - Walker, David

AU - Greenblatt, Martha

PY - 2015/4/1

Y1 - 2015/4/1

N2 - Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (PS) of 67.8 μC cm-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

AB - Mn2+2Fe2+W6+O6, a new polar magnetic phase, adopts the corundum-derived Ni3TeO6-type structure with large spontaneous polarization (PS) of 67.8 μC cm-2, complex antiferromagnetic order below ≈75 K, and field-induced first-order transition to a ferrimagnetic phase below ≈30 K. First-principles calculations predict a ferrimagnetic (udu) ground state, optimal switching path along the c-axis, and transition to a lower energy udu-udd magnetic double cell.

UR - https://www.scopus.com/pages/publications/85027951696

UR - https://www.scopus.com/pages/publications/85027951696#tab=citedBy

U2 - 10.1002/adma.201405244

DO - 10.1002/adma.201405244

M3 - Article

AN - SCOPUS:85027951696

SN - 0935-9648

VL - 27

SP - 2177

EP - 2181

JO - Advanced Materials

JF - Advanced Materials

IS - 13

ER -

Mn₂FeWO₆: A New Ni₃TeO₆-Type Polar and Magnetic Oxide

Abstract

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