Modulation of dendritic patterns during electrodeposition: A nonlinear phase-field model

Lei Chen; Hao Wei Zhang; Lin Yun Liang; Zhe Liu; Yue Qi; Peng Lu; James Chen; Long Qing Chen

doi:10.1016/j.jpowsour.2015.09.055

Modulation of dendritic patterns during electrodeposition: A nonlinear phase-field model

Lei Chen, Hao Wei Zhang, Lin Yun Liang, Zhe Liu, Yue Qi, Peng Lu, James Chen, Long Qing Chen

Research output: Contribution to journal › Article › peer-review

267 Scopus citations

Abstract

A nonlinear phase-field model, accounting for the Butler-Volmer electrochemical reaction kinetics, is developed to investigate the dendritic patterns during an electrodeposition process. Using lithium electrodeposition as an example, the proposed model is first verified by comparison with the Nernst equation in a 1D equilibrium system. The nonlinear electrochemical kinetics is also confirmed at non-equilibrium condition. The dendritic patterns are examined as a function of applied voltage and initial electrode surface morphology. A design map is proposed to tailor the electrode surface morphology and the applied voltage to avoid undesired dendritic patterns.

Original language	English (US)
Pages (from-to)	376-385
Number of pages	10
Journal	Journal of Power Sources
Volume	300
DOIs	https://doi.org/10.1016/j.jpowsour.2015.09.055
State	Published - Dec 30 2015

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

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10.1016/j.jpowsour.2015.09.055

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title = "Modulation of dendritic patterns during electrodeposition: A nonlinear phase-field model",

abstract = "A nonlinear phase-field model, accounting for the Butler-Volmer electrochemical reaction kinetics, is developed to investigate the dendritic patterns during an electrodeposition process. Using lithium electrodeposition as an example, the proposed model is first verified by comparison with the Nernst equation in a 1D equilibrium system. The nonlinear electrochemical kinetics is also confirmed at non-equilibrium condition. The dendritic patterns are examined as a function of applied voltage and initial electrode surface morphology. A design map is proposed to tailor the electrode surface morphology and the applied voltage to avoid undesired dendritic patterns.",

author = "Lei Chen and Zhang, {Hao Wei} and Liang, {Lin Yun} and Zhe Liu and Yue Qi and Peng Lu and James Chen and Chen, {Long Qing}",

note = "Funding Information: The authors are grateful for the financial support by NSF under CMMI-1235092 . The computer simulations were carried out on the LION clusters at the Pennsylvania State University. ",

year = "2015",

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doi = "10.1016/j.jpowsour.2015.09.055",

language = "English (US)",

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TY - JOUR

T1 - Modulation of dendritic patterns during electrodeposition

T2 - A nonlinear phase-field model

AU - Chen, Lei

AU - Zhang, Hao Wei

AU - Liang, Lin Yun

AU - Liu, Zhe

AU - Qi, Yue

AU - Lu, Peng

AU - Chen, James

AU - Chen, Long Qing

N1 - Funding Information: The authors are grateful for the financial support by NSF under CMMI-1235092 . The computer simulations were carried out on the LION clusters at the Pennsylvania State University.

PY - 2015/12/30

Y1 - 2015/12/30

N2 - A nonlinear phase-field model, accounting for the Butler-Volmer electrochemical reaction kinetics, is developed to investigate the dendritic patterns during an electrodeposition process. Using lithium electrodeposition as an example, the proposed model is first verified by comparison with the Nernst equation in a 1D equilibrium system. The nonlinear electrochemical kinetics is also confirmed at non-equilibrium condition. The dendritic patterns are examined as a function of applied voltage and initial electrode surface morphology. A design map is proposed to tailor the electrode surface morphology and the applied voltage to avoid undesired dendritic patterns.

AB - A nonlinear phase-field model, accounting for the Butler-Volmer electrochemical reaction kinetics, is developed to investigate the dendritic patterns during an electrodeposition process. Using lithium electrodeposition as an example, the proposed model is first verified by comparison with the Nernst equation in a 1D equilibrium system. The nonlinear electrochemical kinetics is also confirmed at non-equilibrium condition. The dendritic patterns are examined as a function of applied voltage and initial electrode surface morphology. A design map is proposed to tailor the electrode surface morphology and the applied voltage to avoid undesired dendritic patterns.

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M3 - Article

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EP - 385

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Modulation of dendritic patterns during electrodeposition: A nonlinear phase-field model

Abstract

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