Molecular logic gates using surface-enhanced raman-scattered light

Edward H. Witlicki; Carsten Johnsen; Stinne W. Hansen; Daniel W. Silverstein; Vincent J. Bottomley; Jan O. Jeppesen; Eric W. Wong; Lasse Jensen; Amar H. Flood

doi:10.1021/ja200992x

Molecular logic gates using surface-enhanced raman-scattered light

Edward H. Witlicki, Carsten Johnsen, Stinne W. Hansen, Daniel W. Silverstein, Vincent J. Bottomley, Jan O. Jeppesen, Eric W. Wong, Lasse Jensen, Amar H. Flood

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

A voltage-activated molecular-plasmonics device was created to demonstrate molecular logic based on resonant surface-enhanced Raman scattering (SERS). SERS output was achieved by a combination of chromophore-plasmon coupling and surface adsorption at the interface between a solution and a gold nanodisc array. The chromophore was created by the self-assembly of a supramolecular complex with a redox-active guest molecule. The guest was reversibly oxidized at the gold surface to the +1 and +2 oxidation states, revealing spectra that were reproduced by calculations. State-specific SERS features enabled the demonstration of a multigate logic device with electronic input and optical output.

Original language	English (US)
Pages (from-to)	7288-7291
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	19
DOIs	https://doi.org/10.1021/ja200992x
State	Published - May 18 2011

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja200992x

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title = "Molecular logic gates using surface-enhanced raman-scattered light",

abstract = "A voltage-activated molecular-plasmonics device was created to demonstrate molecular logic based on resonant surface-enhanced Raman scattering (SERS). SERS output was achieved by a combination of chromophore-plasmon coupling and surface adsorption at the interface between a solution and a gold nanodisc array. The chromophore was created by the self-assembly of a supramolecular complex with a redox-active guest molecule. The guest was reversibly oxidized at the gold surface to the +1 and +2 oxidation states, revealing spectra that were reproduced by calculations. State-specific SERS features enabled the demonstration of a multigate logic device with electronic input and optical output.",

author = "Witlicki, {Edward H.} and Carsten Johnsen and Hansen, {Stinne W.} and Silverstein, {Daniel W.} and Bottomley, {Vincent J.} and Jeppesen, {Jan O.} and Wong, {Eric W.} and Lasse Jensen and Flood, {Amar H.}",

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T1 - Molecular logic gates using surface-enhanced raman-scattered light

AU - Witlicki, Edward H.

AU - Johnsen, Carsten

AU - Hansen, Stinne W.

AU - Silverstein, Daniel W.

AU - Bottomley, Vincent J.

AU - Jeppesen, Jan O.

AU - Wong, Eric W.

AU - Jensen, Lasse

AU - Flood, Amar H.

PY - 2011/5/18

Y1 - 2011/5/18

N2 - A voltage-activated molecular-plasmonics device was created to demonstrate molecular logic based on resonant surface-enhanced Raman scattering (SERS). SERS output was achieved by a combination of chromophore-plasmon coupling and surface adsorption at the interface between a solution and a gold nanodisc array. The chromophore was created by the self-assembly of a supramolecular complex with a redox-active guest molecule. The guest was reversibly oxidized at the gold surface to the +1 and +2 oxidation states, revealing spectra that were reproduced by calculations. State-specific SERS features enabled the demonstration of a multigate logic device with electronic input and optical output.

AB - A voltage-activated molecular-plasmonics device was created to demonstrate molecular logic based on resonant surface-enhanced Raman scattering (SERS). SERS output was achieved by a combination of chromophore-plasmon coupling and surface adsorption at the interface between a solution and a gold nanodisc array. The chromophore was created by the self-assembly of a supramolecular complex with a redox-active guest molecule. The guest was reversibly oxidized at the gold surface to the +1 and +2 oxidation states, revealing spectra that were reproduced by calculations. State-specific SERS features enabled the demonstration of a multigate logic device with electronic input and optical output.

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Molecular logic gates using surface-enhanced raman-scattered light

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