Mono- and di-nuclear azido η6-p-cymene ruthenium(II) complexes; synthesis, reactivity, and structures

R. Lalrempuia; Hemant P. Yennawar; Mohan Rao Kollipara

doi:10.1080/00958970903154470

Mono- and di-nuclear azido η⁶-p-cymene ruthenium(II) complexes; synthesis, reactivity, and structures

R. Lalrempuia, Hemant P. Yennawar, Mohan Rao Kollipara

Biochemistry & Molecular Biology

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The azide bridge complex [(η⁶-p-cymene)Ru(μ-N3)Cl]₂ (2) was prepared from the reaction of sodium azide with [(η⁶-p-cymene)RuCl]₂ in ethanol. The molecular structures and spectroscopic properties of the various azido ruthenium complexes so obtained from the reaction with monodentate and bidentate ligands are described.

Original language	English (US)
Pages (from-to)	3661-3678
Number of pages	18
Journal	Journal of Coordination Chemistry
Volume	62
Issue number	22
DOIs	https://doi.org/10.1080/00958970903154470
State	Published - Nov 2009

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958970903154470

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title = "Mono- and di-nuclear azido η6-p-cymene ruthenium(II) complexes; synthesis, reactivity, and structures",

abstract = "The azide bridge complex [(η6-p-cymene)Ru(μ-N3)Cl]2 (2) was prepared from the reaction of sodium azide with [(η6-p-cymene)RuCl]2 in ethanol. The molecular structures and spectroscopic properties of the various azido ruthenium complexes so obtained from the reaction with monodentate and bidentate ligands are described.",

author = "R. Lalrempuia and Yennawar, {Hemant P.} and Kollipara, {Mohan Rao}",

note = "Funding Information: R. Lalrempuia would like to thank the Council of Scientific and Industrial Research, India, for SRF fellowship and H.P. Yennawar thanks NSF grant CHE-0131112 for X-ray facility.",

year = "2009",

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doi = "10.1080/00958970903154470",

language = "English (US)",

volume = "62",

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AU - Lalrempuia, R.

AU - Yennawar, Hemant P.

AU - Kollipara, Mohan Rao

N1 - Funding Information: R. Lalrempuia would like to thank the Council of Scientific and Industrial Research, India, for SRF fellowship and H.P. Yennawar thanks NSF grant CHE-0131112 for X-ray facility.

PY - 2009/11

Y1 - 2009/11

N2 - The azide bridge complex [(η6-p-cymene)Ru(μ-N3)Cl]2 (2) was prepared from the reaction of sodium azide with [(η6-p-cymene)RuCl]2 in ethanol. The molecular structures and spectroscopic properties of the various azido ruthenium complexes so obtained from the reaction with monodentate and bidentate ligands are described.

AB - The azide bridge complex [(η6-p-cymene)Ru(μ-N3)Cl]2 (2) was prepared from the reaction of sodium azide with [(η6-p-cymene)RuCl]2 in ethanol. The molecular structures and spectroscopic properties of the various azido ruthenium complexes so obtained from the reaction with monodentate and bidentate ligands are described.

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ER -

Mono- and di-nuclear azido η⁶-p-cymene ruthenium(II) complexes; synthesis, reactivity, and structures

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