TY - JOUR
T1 - Movement of manganese contamination through the Critical Zone
AU - Herndon, Elizabeth M.
AU - Brantley, Susan L.
N1 - Funding Information:
This material is based upon work supported by the National Science Foundation under Grant No. CHE-0431328 for the Center for Environmental Kinetics Analysis and under Grant No. EAR-0725019 for the Susquehanna/Shale Hills Critical Zone Observatory. The authors acknowledge Peter Raymond for the supply and helpful discussion of river chemistry data.
PY - 2011/6
Y1 - 2011/6
N2 - Humans have transferred large quantities of metals from the lithosphere to the Earth's surface, drastically altering the natural flow of these elements. The geographic dispersal of many metals and their impacts on the environment are unknown. Here, existing datasets are compiled to assess how anthropogenic inputs of Mn to the air have altered soil and water chemistry over time. Although levels of Mn in the air have declined in recent decades, soils throughout the USA and Europe are enriched in Mn, revealing past contamination near zones of industrial input. Examination of river chemistry indicates a similar decline in Mn and can be used to evaluate the removal of Mn from soils. We use a small watershed, the Susquehanna/Shale Hills Critical Zone Observatory, as a focus site to investigate geochemical mass balance models and find that rapid biocycling contributes to the retention of Mn in this affected ecosystem.
AB - Humans have transferred large quantities of metals from the lithosphere to the Earth's surface, drastically altering the natural flow of these elements. The geographic dispersal of many metals and their impacts on the environment are unknown. Here, existing datasets are compiled to assess how anthropogenic inputs of Mn to the air have altered soil and water chemistry over time. Although levels of Mn in the air have declined in recent decades, soils throughout the USA and Europe are enriched in Mn, revealing past contamination near zones of industrial input. Examination of river chemistry indicates a similar decline in Mn and can be used to evaluate the removal of Mn from soils. We use a small watershed, the Susquehanna/Shale Hills Critical Zone Observatory, as a focus site to investigate geochemical mass balance models and find that rapid biocycling contributes to the retention of Mn in this affected ecosystem.
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U2 - 10.1016/j.apgeochem.2011.03.024
DO - 10.1016/j.apgeochem.2011.03.024
M3 - Article
AN - SCOPUS:79955963896
SN - 0883-2927
VL - 26
SP - S40-S43
JO - Applied Geochemistry
JF - Applied Geochemistry
IS - SUPPL.
ER -