New catalyst system for the synthesis of linear α-olefins

C. Andes; Jr Wojcinski L.; A. Sen

New catalyst system for the synthesis of linear α-olefins

C. Andes, Jr Wojcinski L., A. Sen

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

A new catalyst system for the synthesis of linear α-olefins from ethylene was developed using zirconium(IV) ethoxide and ethylaluminum dichloride. The addition of diethylzinc significantly improved the activity of the system. The addition of acetylacetone decreased branching, resulting in α-olefins that are > 99% linear. The α-olefins chain length from this system are C₄-C₃₀.

Original language	English (US)
Pages (from-to)	INOR-565
Journal	ACS National Meeting Book of Abstracts
Volume	PART 1
State	Published - 1999
Event	Proceedings of the 1999 218th ACS National Meeting - New Oeleans, LA, United States Duration: Aug 22 1999 → Aug 26 1999

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

Cite this

@article{9140b705d68f4da7af05a6d3152e91a3,

title = "New catalyst system for the synthesis of linear α-olefins",

abstract = "A new catalyst system for the synthesis of linear α-olefins from ethylene was developed using zirconium(IV) ethoxide and ethylaluminum dichloride. The addition of diethylzinc significantly improved the activity of the system. The addition of acetylacetone decreased branching, resulting in α-olefins that are > 99% linear. The α-olefins chain length from this system are C4-C30.",

author = "C. Andes and {Wojcinski L.}, Jr and A. Sen",

year = "1999",

language = "English (US)",

volume = "PART 1",

pages = "INOR--565",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

publisher = "American Chemical Society",

note = "Proceedings of the 1999 218th ACS National Meeting ; Conference date: 22-08-1999 Through 26-08-1999",

}

TY - JOUR

T1 - New catalyst system for the synthesis of linear α-olefins

AU - Andes, C.

AU - Wojcinski L., Jr

AU - Sen, A.

PY - 1999

Y1 - 1999

N2 - A new catalyst system for the synthesis of linear α-olefins from ethylene was developed using zirconium(IV) ethoxide and ethylaluminum dichloride. The addition of diethylzinc significantly improved the activity of the system. The addition of acetylacetone decreased branching, resulting in α-olefins that are > 99% linear. The α-olefins chain length from this system are C4-C30.

AB - A new catalyst system for the synthesis of linear α-olefins from ethylene was developed using zirconium(IV) ethoxide and ethylaluminum dichloride. The addition of diethylzinc significantly improved the activity of the system. The addition of acetylacetone decreased branching, resulting in α-olefins that are > 99% linear. The α-olefins chain length from this system are C4-C30.

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UR - http://www.scopus.com/inward/citedby.url?scp=16744362104&partnerID=8YFLogxK

M3 - Comment/debate

AN - SCOPUS:16744362104

SN - 0065-7727

VL - PART 1

SP - INOR-565

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - Proceedings of the 1999 218th ACS National Meeting

Y2 - 22 August 1999 through 26 August 1999

ER -

New catalyst system for the synthesis of linear α-olefins

Abstract

All Science Journal Classification (ASJC) codes

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