New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics

Richard E. Eitel; Clive A. Randall; Thomas R. Shrout; Paul W. Rehrig; Wes Hackenberger; Seung Eek Park

doi:10.1143/jjap.40.5999

New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O₃-PbTiO₃ ceramics

Richard E. Eitel
, Clive A. Randall
, Thomas R. Shrout
, Paul W. Rehrig
, Wes Hackenberger
, Seung Eek Park

Research output: Contribution to journal › Article › peer-review

891 Scopus citations

Abstract

New morphotropic phase boundary (MPB) piezoelectrics, with ferroelectric phase transition (T_c) exceeding that of PbZrO₃-PbTiO₃ (PZT), were investigated. Based on a perovskite tolerance factor-T_c relationship, new high T_c MPB systems were projected in the Bi(Me)O₃-PbTiO₃ system, where Me is a relatively large B⁺³-site cation. For the (1 - x)BiScO₃-(x)PbTiO₃ solid solution, a MPB was found at x-0.64 separating the rhombohedral and tetragonal phases, with correspondingly enhanced dielectric and piezoelectric properties. A transition temperature T_c of ∼ 450°C was determined with evidence of T_c's on the order of ≥ 600°C in the BiInO₃ and BiYbO₃ analogues, though issues of perovsk stability remain for the smaller tolerance end-member systems.

Original language	English (US)
Pages (from-to)	5999-6002
Number of pages	4
Journal	Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume	40
Issue number	10
DOIs	https://doi.org/10.1143/jjap.40.5999
State	Published - Oct 2001

All Science Journal Classification (ASJC) codes

General Engineering
General Physics and Astronomy

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10.1143/jjap.40.5999

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title = "New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics",

abstract = "New morphotropic phase boundary (MPB) piezoelectrics, with ferroelectric phase transition (Tc) exceeding that of PbZrO3-PbTiO3 (PZT), were investigated. Based on a perovskite tolerance factor-Tc relationship, new high Tc MPB systems were projected in the Bi(Me)O3-PbTiO3 system, where Me is a relatively large B+3-site cation. For the (1 - x)BiScO3-(x)PbTiO3 solid solution, a MPB was found at x-0.64 separating the rhombohedral and tetragonal phases, with correspondingly enhanced dielectric and piezoelectric properties. A transition temperature Tc of ∼ 450°C was determined with evidence of Tc's on the order of ≥ 600°C in the BiInO3 and BiYbO3 analogues, though issues of perovsk stability remain for the smaller tolerance end-member systems.",

author = "Eitel, \{Richard E.\} and Randall, \{Clive A.\} and Shrout, \{Thomas R.\} and Rehrig, \{Paul W.\} and Wes Hackenberger and Park, \{Seung Eek\}",

year = "2001",

month = oct,

doi = "10.1143/jjap.40.5999",

language = "English (US)",

volume = "40",

pages = "5999--6002",

journal = "Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers",

issn = "0021-4922",

publisher = "Institute of Physics",

number = "10",

}

New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O₃-PbTiO₃ ceramics. / Eitel, Richard E.; Randall, Clive A.; Shrout, Thomas R. et al.
In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 40, No. 10, 10.2001, p. 5999-6002.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O3-PbTiO3 ceramics

AU - Eitel, Richard E.

AU - Randall, Clive A.

AU - Shrout, Thomas R.

AU - Rehrig, Paul W.

AU - Hackenberger, Wes

AU - Park, Seung Eek

PY - 2001/10

Y1 - 2001/10

N2 - New morphotropic phase boundary (MPB) piezoelectrics, with ferroelectric phase transition (Tc) exceeding that of PbZrO3-PbTiO3 (PZT), were investigated. Based on a perovskite tolerance factor-Tc relationship, new high Tc MPB systems were projected in the Bi(Me)O3-PbTiO3 system, where Me is a relatively large B+3-site cation. For the (1 - x)BiScO3-(x)PbTiO3 solid solution, a MPB was found at x-0.64 separating the rhombohedral and tetragonal phases, with correspondingly enhanced dielectric and piezoelectric properties. A transition temperature Tc of ∼ 450°C was determined with evidence of Tc's on the order of ≥ 600°C in the BiInO3 and BiYbO3 analogues, though issues of perovsk stability remain for the smaller tolerance end-member systems.

AB - New morphotropic phase boundary (MPB) piezoelectrics, with ferroelectric phase transition (Tc) exceeding that of PbZrO3-PbTiO3 (PZT), were investigated. Based on a perovskite tolerance factor-Tc relationship, new high Tc MPB systems were projected in the Bi(Me)O3-PbTiO3 system, where Me is a relatively large B+3-site cation. For the (1 - x)BiScO3-(x)PbTiO3 solid solution, a MPB was found at x-0.64 separating the rhombohedral and tetragonal phases, with correspondingly enhanced dielectric and piezoelectric properties. A transition temperature Tc of ∼ 450°C was determined with evidence of Tc's on the order of ≥ 600°C in the BiInO3 and BiYbO3 analogues, though issues of perovsk stability remain for the smaller tolerance end-member systems.

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DO - 10.1143/jjap.40.5999

M3 - Article

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SN - 0021-4922

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JO - Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers

JF - Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers

IS - 10

ER -

New high temperature morphotropic phase boundary piezoelectrics based on Bi(Me)O₃-PbTiO₃ ceramics

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