TY - JOUR
T1 - New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles
AU - Allcock, Harry R.
AU - Diefenbach, Ursula
AU - Pucher, Shawn R.
PY - 1994/7/1
Y1 - 1994/7/1
N2 - Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.
AB - Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.
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U2 - 10.1021/ic00092a013
DO - 10.1021/ic00092a013
M3 - Article
AN - SCOPUS:0001275876
SN - 0020-1669
VL - 33
SP - 3091
EP - 3095
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 14
ER -