New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles

Harry R. Allcock; Ursula Diefenbach; Shawn R. Pucher

doi:10.1021/ic00092a013

New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl₂)₃ with Aromatic Ortho Dinucleophiles

Harry R. Allcock
, Ursula Diefenbach
, Shawn R. Pucher

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, ³¹P NMR, and ¹H NMR spectroscopy, mass spectrometry, and elemental analysis.

Original language	English (US)
Pages (from-to)	3091-3095
Number of pages	5
Journal	Inorganic Chemistry
Volume	33
Issue number	14
DOIs	https://doi.org/10.1021/ic00092a013
State	Published - Jul 1 1994

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00092a013

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title = "New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles",

abstract = "Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.",

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year = "1994",

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doi = "10.1021/ic00092a013",

language = "English (US)",

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journal = "Inorganic Chemistry",

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T1 - New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl2)3 with Aromatic Ortho Dinucleophiles

AU - Allcock, Harry R.

AU - Diefenbach, Ursula

AU - Pucher, Shawn R.

PY - 1994/7/1

Y1 - 1994/7/1

N2 - Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.

AB - Hexachlorotriphosphazene reacted with 1,2-diaminobenzene, 1,2-diamino-4-methylbenzene, 1,2-diamino-4,5-dimethylbenzene, 1,2-diamino-4,5-dichlorobenzene, 2,3-diaminonaphthalene, 9,10-diaminophenanthrene, 2,3-diaminopyridine, trans 1,2-diaminocyclohexane, 1,2-diaminobenzophenone, and 1,2-benzenedithiol in THF in the presence of triethylamine to give the corresponding mono- or trispirocyclotriphosphazenes. The structures were examined by IR, 31P NMR, and 1H NMR spectroscopy, mass spectrometry, and elemental analysis.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 14

ER -

New Mono- and Trispirocyclotriphosphazenes from the Reactions of (NPCl₂)₃ with Aromatic Ortho Dinucleophiles

Abstract

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