TY - JOUR
T1 - New olefin polymerization and copolymerization catalysts. Effect of coordinating functionalities
AU - Sen, Ayusman
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 2001
Y1 - 2001
N2 - The coordination of the functionalities that may be present either in the monomer or in the growing polymer chain to the metal center is a key impediment in the development of new transition metal-based catalysts for the insertion polymerization of polar monomers. Several examples are discussed to illustrate this problem. Additionally, it is shown that the reduction of the electrophilicity of the metal center is one way to decrease this interaction.
AB - The coordination of the functionalities that may be present either in the monomer or in the growing polymer chain to the metal center is a key impediment in the development of new transition metal-based catalysts for the insertion polymerization of polar monomers. Several examples are discussed to illustrate this problem. Additionally, it is shown that the reduction of the electrophilicity of the metal center is one way to decrease this interaction.
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U2 - 10.1351/pac200173020251
DO - 10.1351/pac200173020251
M3 - Article
AN - SCOPUS:0035742999
SN - 0033-4545
VL - 73
SP - 251
EP - 254
JO - Pure and Applied Chemistry
JF - Pure and Applied Chemistry
IS - 2
ER -