Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes

Laura M. Wickham; Roshan K. Dhungana; Ramesh Giri

doi:10.1021/acsomega.2c06417

Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes

Laura M. Wickham, Roshan K. Dhungana, Ramesh Giri

Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.

Original language	English (US)
Pages (from-to)	1060-1066
Number of pages	7
Journal	ACS Omega
Volume	8
Issue number	1
DOIs	https://doi.org/10.1021/acsomega.2c06417
State	Published - Jan 10 2023

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

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10.1021/acsomega.2c06417

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title = "Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes",

abstract = "Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.",

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AU - Dhungana, Roshan K.

AU - Giri, Ramesh

PY - 2023/1/10

Y1 - 2023/1/10

N2 - Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.

AB - Dicarbofunctionalization is an important efficient synthetic technique for adding two chemical moieties across an alkene. Here, a novel method of reductive dicarbofunctionalization has been developed using a single alkenyl triflate as the electrophile, combined with an unactivated alkene. The reaction does not require an external auxiliary and proceeds with complete regioselectivity.

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Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes

Abstract

All Science Journal Classification (ASJC) codes

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