(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate

Shawn M. Carter; Nan Xu; Masood A. Khan; Douglas R. Powell; George B. Richter-Addo

doi:10.1107/S1600536808030705

(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ⁴ N)molybdenum(V) benzene solvate

Shawn M. Carter
, Nan Xu
, Masood A. Khan
, Douglas R. Powell
, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

Original language	English (US)
Pages (from-to)	m1337
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	64
Issue number	10
DOIs	https://doi.org/10.1107/S1600536808030705
State	Published - 2008

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate",

abstract = "In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) {\AA} towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.",

author = "Carter, \{Shawn M.\} and Nan Xu and Khan, \{Masood A.\} and Powell, \{Douglas R.\} and Richter-Addo, \{George B.\}",

year = "2008",

doi = "10.1107/S1600536808030705",

language = "English (US)",

volume = "64",

pages = "m1337",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - (Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ4 N)molybdenum(V) benzene solvate

AU - Carter, Shawn M.

AU - Xu, Nan

AU - Khan, Masood A.

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2008

Y1 - 2008

N2 - In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

AB - In the title compound, [Mo(C44H28N4)(NO3)O]·C6H6, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo - O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

UR - https://www.scopus.com/pages/publications/53349153345

UR - https://www.scopus.com/pages/publications/53349153345#tab=citedBy

U2 - 10.1107/S1600536808030705

DO - 10.1107/S1600536808030705

M3 - Article

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AN - SCOPUS:53349153345

SN - 1600-5368

VL - 64

SP - m1337

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato- κ⁴ N)molybdenum(V) benzene solvate

Abstract

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