TY - JOUR
T1 - Nitrosylation in a crystal
T2 - Remarkable movements of iron porphyrins upon binding of nitric oxide
AU - Xu, Nan
AU - Powell, Douglas R.
AU - Richter-Addo, George B.
PY - 2011/10/4
Y1 - 2011/10/4
N2 - Bustin' a move: Diffusion of NO gas into crystals of [(TPP)Fe(H 2O)]SO 3CF 3 (1) results in nitrosylation of half the number of molecules to generate [(TPP)Fe(NO)(H 2O)]SO 3CF 3 (2). This nitrosylation reaction in the solid phase produces a dramatic movement of the porphyrins to accommodate the NO ligands. The presence of both molecules in the same crystal allows a reliable comparison of their geometric data. TPP=tetraphenylporphyrin; C black, N blue, O red.
AB - Bustin' a move: Diffusion of NO gas into crystals of [(TPP)Fe(H 2O)]SO 3CF 3 (1) results in nitrosylation of half the number of molecules to generate [(TPP)Fe(NO)(H 2O)]SO 3CF 3 (2). This nitrosylation reaction in the solid phase produces a dramatic movement of the porphyrins to accommodate the NO ligands. The presence of both molecules in the same crystal allows a reliable comparison of their geometric data. TPP=tetraphenylporphyrin; C black, N blue, O red.
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U2 - 10.1002/anie.201103329
DO - 10.1002/anie.201103329
M3 - Article
C2 - 21913289
AN - SCOPUS:80053473972
SN - 1433-7851
VL - 50
SP - 9694
EP - 9696
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 41
ER -