Non-vanishing Berry phase in chiral insulators

The binary compounds FeSi, RuSi, and OsSi are chiral insulators crystallizing in the space group P2₁₃ which is cubic. By means of ab initio calculations we find for these compounds a non-vanishing electronic Berry phase, the sign of which depends on the handedness of the crystal. There is thus the possibility that the Berry phase signals the existence of a macroscopic electric polarization due to the electrons. We show that this is indeed so if a small external magnetic field is applied in the [111] direction. The electric polarization is oscillatory in the magnetic field and possesses a signature that distinguishes the handedness of the crystal. Our findings add to the discussion of topological classifications of insulators and are significant for spintronics applications, and in particular, for a deeper understanding of skyrmions in insulators.