Observation of an amplified isotope effect during chlorination of 1-methylpyrrole. Evidence for rate determining deprotonation of the σ-complex

Michael De Rosa; Manuel Marquez

doi:10.1039/C39890001466

Observation of an amplified isotope effect during chlorination of 1-methylpyrrole. Evidence for rate determining deprotonation of the σ-complex

Michael De Rosa
, Manuel Marquez

Penn State Brandywine

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Observation of an amplified isotope effect to the value of 19.10 indicated that there were two kinetically significant proton transfers and deprotonation of the σ-complex was the rate determining step.

Original language	English (US)
Pages (from-to)	1466-1467
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/C39890001466
State	Published - Jan 1 1989

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39890001466

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title = "Observation of an amplified isotope effect during chlorination of 1-methylpyrrole. Evidence for rate determining deprotonation of the σ-complex",

abstract = "Observation of an amplified isotope effect to the value of 19.10 indicated that there were two kinetically significant proton transfers and deprotonation of the σ-complex was the rate determining step.",

author = "\{De Rosa\}, Michael and Manuel Marquez",

year = "1989",

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doi = "10.1039/C39890001466",

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AU - Marquez, Manuel

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Y1 - 1989/1/1

N2 - Observation of an amplified isotope effect to the value of 19.10 indicated that there were two kinetically significant proton transfers and deprotonation of the σ-complex was the rate determining step.

AB - Observation of an amplified isotope effect to the value of 19.10 indicated that there were two kinetically significant proton transfers and deprotonation of the σ-complex was the rate determining step.

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 19

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Observation of an amplified isotope effect during chlorination of 1-methylpyrrole. Evidence for rate determining deprotonation of the σ-complex

Abstract

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