Observation of polymorphic lead monoxide surfaces using x-ray photoelectron spectroscopy

K. S. Kim; N. Winograd

doi:10.1016/0009-2614(73)85056-0

Observation of polymorphic lead monoxide surfaces using x-ray photoelectron spectroscopy

K. S. Kim, N. Winograd

Chemistry

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

The X-ray photoelectron spectra of several lead-oxygen species are reported. During the oxidation of freshly evaporated lead surfaces, chemisorbed oxygen atoms on lead as well as rhombic and tetragonal PbO can be detected. The unique sensitivity of O 1s spectra to the different crystal modification has also allowed the monitoring of a polymorphic transformation on oxide films as thin as a monolayer.

Original language	English (US)
Pages (from-to)	209-212
Number of pages	4
Journal	Chemical Physics Letters
Volume	19
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(73)85056-0
State	Published - Mar 15 1973

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(73)85056-0

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@article{07daa457e6d2488bb87c9d4474af3325,

title = "Observation of polymorphic lead monoxide surfaces using x-ray photoelectron spectroscopy",

abstract = "The X-ray photoelectron spectra of several lead-oxygen species are reported. During the oxidation of freshly evaporated lead surfaces, chemisorbed oxygen atoms on lead as well as rhombic and tetragonal PbO can be detected. The unique sensitivity of O 1s spectra to the different crystal modification has also allowed the monitoring of a polymorphic transformation on oxide films as thin as a monolayer.",

author = "Kim, {K. S.} and N. Winograd",

note = "Funding Information: The authorsw ish to thank the National Science Foundation (Grant No. GP-27744) and the Air Force Office of Scientific Research( Grant No. AFOSR-72-2238) for financial support. The authors also appreciate the equipment grant from the National Science Foundation which allowed purchase of the ESCA; The assistanceo f Jon Amy and William Baitinger is also aclcnowiedged.",

year = "1973",

month = mar,

day = "15",

doi = "10.1016/0009-2614(73)85056-0",

language = "English (US)",

volume = "19",

pages = "209--212",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Observation of polymorphic lead monoxide surfaces using x-ray photoelectron spectroscopy

AU - Kim, K. S.

AU - Winograd, N.

N1 - Funding Information: The authorsw ish to thank the National Science Foundation (Grant No. GP-27744) and the Air Force Office of Scientific Research( Grant No. AFOSR-72-2238) for financial support. The authors also appreciate the equipment grant from the National Science Foundation which allowed purchase of the ESCA; The assistanceo f Jon Amy and William Baitinger is also aclcnowiedged.

PY - 1973/3/15

Y1 - 1973/3/15

N2 - The X-ray photoelectron spectra of several lead-oxygen species are reported. During the oxidation of freshly evaporated lead surfaces, chemisorbed oxygen atoms on lead as well as rhombic and tetragonal PbO can be detected. The unique sensitivity of O 1s spectra to the different crystal modification has also allowed the monitoring of a polymorphic transformation on oxide films as thin as a monolayer.

AB - The X-ray photoelectron spectra of several lead-oxygen species are reported. During the oxidation of freshly evaporated lead surfaces, chemisorbed oxygen atoms on lead as well as rhombic and tetragonal PbO can be detected. The unique sensitivity of O 1s spectra to the different crystal modification has also allowed the monitoring of a polymorphic transformation on oxide films as thin as a monolayer.

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U2 - 10.1016/0009-2614(73)85056-0

DO - 10.1016/0009-2614(73)85056-0

M3 - Article

AN - SCOPUS:0039965225

SN - 0009-2614

VL - 19

SP - 209

EP - 212

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

Observation of polymorphic lead monoxide surfaces using x-ray photoelectron spectroscopy

Abstract

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