On the (uninteresting) dependence of the absorption and emission transition moments of coumarin 153 on solvent

J. E. Lewis; M. Maroncelli

doi:10.1016/S0009-2614(97)01270-0

On the (uninteresting) dependence of the absorption and emission transition moments of coumarin 153 on solvent

J. E. Lewis, M. Maroncelli

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Abstract

The absorption and emission transition moments of coumarin 153 as well as fluorescence lifetimes and quantum yields were measured over a broad range of solvents in which the absorption and emission frequencies varied substantially. The same value was found for both the absorption and emission transition moments, and both also were found to be independent of solvent. These results suggest that a simple two electronic state model for the S₀↔S₁ transition in coumarin 153 is entirely appropriate.

Original language	English (US)
Pages (from-to)	197-203
Number of pages	7
Journal	Chemical Physics Letters
Volume	282
Issue number	2
DOIs	https://doi.org/10.1016/S0009-2614(97)01270-0
State	Published - Jan 9 1998

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/S0009-2614(97)01270-0

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title = "On the (uninteresting) dependence of the absorption and emission transition moments of coumarin 153 on solvent",

abstract = "The absorption and emission transition moments of coumarin 153 as well as fluorescence lifetimes and quantum yields were measured over a broad range of solvents in which the absorption and emission frequencies varied substantially. The same value was found for both the absorption and emission transition moments, and both also were found to be independent of solvent. These results suggest that a simple two electronic state model for the S0↔S1 transition in coumarin 153 is entirely appropriate.",

author = "Lewis, {J. E.} and M. Maroncelli",

note = "Funding Information: Financial support for this study was provided by the Office of Basic Energy Sciences of the Department of Energy.",

year = "1998",

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doi = "10.1016/S0009-2614(97)01270-0",

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T1 - On the (uninteresting) dependence of the absorption and emission transition moments of coumarin 153 on solvent

AU - Lewis, J. E.

AU - Maroncelli, M.

N1 - Funding Information: Financial support for this study was provided by the Office of Basic Energy Sciences of the Department of Energy.

PY - 1998/1/9

Y1 - 1998/1/9

N2 - The absorption and emission transition moments of coumarin 153 as well as fluorescence lifetimes and quantum yields were measured over a broad range of solvents in which the absorption and emission frequencies varied substantially. The same value was found for both the absorption and emission transition moments, and both also were found to be independent of solvent. These results suggest that a simple two electronic state model for the S0↔S1 transition in coumarin 153 is entirely appropriate.

AB - The absorption and emission transition moments of coumarin 153 as well as fluorescence lifetimes and quantum yields were measured over a broad range of solvents in which the absorption and emission frequencies varied substantially. The same value was found for both the absorption and emission transition moments, and both also were found to be independent of solvent. These results suggest that a simple two electronic state model for the S0↔S1 transition in coumarin 153 is entirely appropriate.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2

ER -

On the (uninteresting) dependence of the absorption and emission transition moments of coumarin 153 on solvent

Abstract

All Science Journal Classification (ASJC) codes

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