One-step topochemical transformation of MoAlB into metastable Mo2AlB2 using a metal chloride salt reaction

Katelyn J. Baumler; Owen S. Adams; Raymond E. Schaak

doi:10.1039/d3cc00138e

One-step topochemical transformation of MoAlB into metastable Mo₂AlB₂ using a metal chloride salt reaction

Katelyn J. Baumler, Owen S. Adams, Raymond E. Schaak

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Reacting MoAlB with ZnCl₂ at 550 °C produces metastable Mo₂AlB₂ through a one-step topochemical transformation. This reaction showcases differences in reactivity between boride-based MAB phases and carbide-based MAX phases, which are solid-state precursors to an important family of 2-D materials.

Original language	English (US)
Pages (from-to)	4814-4817
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	32
DOIs	https://doi.org/10.1039/d3cc00138e
State	Published - Mar 17 2023

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Catalysis

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10.1039/d3cc00138e

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title = "One-step topochemical transformation of MoAlB into metastable Mo2AlB2 using a metal chloride salt reaction",

abstract = "Reacting MoAlB with ZnCl2 at 550 °C produces metastable Mo2AlB2 through a one-step topochemical transformation. This reaction showcases differences in reactivity between boride-based MAB phases and carbide-based MAX phases, which are solid-state precursors to an important family of 2-D materials.",

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AU - Baumler, Katelyn J.

AU - Adams, Owen S.

AU - Schaak, Raymond E.

PY - 2023/3/17

Y1 - 2023/3/17

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AB - Reacting MoAlB with ZnCl2 at 550 °C produces metastable Mo2AlB2 through a one-step topochemical transformation. This reaction showcases differences in reactivity between boride-based MAB phases and carbide-based MAX phases, which are solid-state precursors to an important family of 2-D materials.

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One-step topochemical transformation of MoAlB into metastable Mo₂AlB₂ using a metal chloride salt reaction

Abstract

All Science Journal Classification (ASJC) codes

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