Organic nanocrystals of [2.2]paracyclophanes achieved via sonochemistry: Enhanced and red-shifted emission involving edge-to-face chromophores

Elizabeth Elacqua; Paul T. Jurgens; Jonas Baltrusaitis; Leonard R. MacGillivray

doi:10.1039/c2ce26000j

Organic nanocrystals of [2.2]paracyclophanes achieved via sonochemistry: Enhanced and red-shifted emission involving edge-to-face chromophores

Elizabeth Elacqua, Paul T. Jurgens, Jonas Baltrusaitis, Leonard R. MacGillivray

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

We have prepared organic nanocrystals of [2.2]paracyclophane (pCp) and tetrakis(4-pyridylcyclobutyl)[2.2]paracyclophane (tpcp) via sonochemistry. Both nanocrystals exhibit an enhanced fluorescence compared to dilute solution, while the tpcp nanocrystals also demonstrate a red-shifted fluorescence.

Original language	English (US)
Pages (from-to)	7567-7571
Number of pages	5
Journal	CrystEngComm
Volume	14
Issue number	22
DOIs	https://doi.org/10.1039/c2ce26000j
State	Published - Nov 21 2012

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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abstract = "We have prepared organic nanocrystals of [2.2]paracyclophane (pCp) and tetrakis(4-pyridylcyclobutyl)[2.2]paracyclophane (tpcp) via sonochemistry. Both nanocrystals exhibit an enhanced fluorescence compared to dilute solution, while the tpcp nanocrystals also demonstrate a red-shifted fluorescence.",

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AU - Elacqua, Elizabeth

AU - Jurgens, Paul T.

AU - Baltrusaitis, Jonas

AU - MacGillivray, Leonard R.

PY - 2012/11/21

Y1 - 2012/11/21

N2 - We have prepared organic nanocrystals of [2.2]paracyclophane (pCp) and tetrakis(4-pyridylcyclobutyl)[2.2]paracyclophane (tpcp) via sonochemistry. Both nanocrystals exhibit an enhanced fluorescence compared to dilute solution, while the tpcp nanocrystals also demonstrate a red-shifted fluorescence.

AB - We have prepared organic nanocrystals of [2.2]paracyclophane (pCp) and tetrakis(4-pyridylcyclobutyl)[2.2]paracyclophane (tpcp) via sonochemistry. Both nanocrystals exhibit an enhanced fluorescence compared to dilute solution, while the tpcp nanocrystals also demonstrate a red-shifted fluorescence.

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Organic nanocrystals of [2.2]paracyclophanes achieved via sonochemistry: Enhanced and red-shifted emission involving edge-to-face chromophores

Abstract

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