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Organic solvent dispersed TiO2 nanocrystal sol: Synthesis and characterization

  • Yuan Qiao Rao
  • , Brian Antalek
  • , John Minter
  • , Thomas Mourey
  • , Thomas Blanton
  • , Gary Slater
  • , Lisa Slater
  • , Jill Fornalik

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Anatase TiO2 nanoparticles with a mean diameter of approximately 10 nm were successfully synthesized by a nonaqueous sol-gel route without the use of air-free equipment. The nanoparticles are well dispersed in common organic solvents in the form of primary particles, and the colloid is stable for more than one year. The particles and colloid were studied by X-ray diffraction (XRD), transmission electron microscope (TEM), atomic-force microscopy (AFM), quasielastic light scattering (QELS), nuclear magnetic resonance (NMR) spectroscopy, and size-exclusion chromatography (SEC). The average particle size measured by several analytical methods is in excellent agreement. Moreover, NMR and SEC are able to detect the presence of an additional component comprising a second population of smaller particles with a diameter of 2 nm. The work in this paper shows that nanotechnology can benefit significantly from the new application of conventional analytical tools.

Original languageEnglish (US)
Title of host publicationNanotechnology 2009
Subtitle of host publicationFabrication, Particles, Characterization, MEMS, Electronics and Photonics - Technical Proceedings of the 2009 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2009
Pages270-272
Number of pages3
StatePublished - 2009
EventNanotechnology 2009: Fabrication, Particles, Characterization, MEMS, Electronics and Photonics - 2009 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2009 - Houston, TX, United States
Duration: May 3 2009May 7 2009

Publication series

NameNanotechnology 2009: Fabrication, Particles, Characterization, MEMS, Electronics and Photonics - Technical Proceedings of the 2009 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2009
Volume1

Conference

ConferenceNanotechnology 2009: Fabrication, Particles, Characterization, MEMS, Electronics and Photonics - 2009 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2009
Country/TerritoryUnited States
CityHouston, TX
Period5/3/095/7/09

All Science Journal Classification (ASJC) codes

  • Electrical and Electronic Engineering
  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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