Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods

Abigail M. Fagan, Benjamin C. Steimle, Raymond E. Schaak

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu+ when multiple products are possible.

Original languageEnglish (US)
Pages (from-to)4328-4331
Number of pages4
JournalChemical Communications
Volume58
Issue number27
DOIs
StatePublished - Mar 3 2022

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • General Chemistry
  • Ceramics and Composites
  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Catalysis

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