Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods

Abigail M. Fagan; Benjamin C. Steimle; Raymond E. Schaak

doi:10.1039/d1cc07190d

Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods

Abigail M. Fagan, Benjamin C. Steimle, Raymond E. Schaak

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu⁺ when multiple products are possible.

Original language	English (US)
Pages (from-to)	4328-4331
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	27
DOIs	https://doi.org/10.1039/d1cc07190d
State	Published - Mar 3 2022

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/d1cc07190d

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title = "Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods",

abstract = "We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu+ when multiple products are possible.",

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AU - Fagan, Abigail M.

AU - Steimle, Benjamin C.

AU - Schaak, Raymond E.

PY - 2022/3/3

Y1 - 2022/3/3

N2 - We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu+ when multiple products are possible.

AB - We report predictive guidelines for the substoichiometric cation exchange of model two-component metal sulfide nanorods containing divalent cations of similar hardness. Unit cell volume changes, cation radii, solubility constants, and solid state interfaces influence selectivity during substoichiometric exchange of Cu+ when multiple products are possible.

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JO - Chemical Communications

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Orthogonal reactivity and interface-driven selectivity during cation exchange of heterostructured metal sulfide nanorods

Abstract

All Science Journal Classification (ASJC) codes

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