TY - JOUR
T1 - Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway
AU - Lin, Minren
AU - Sen, Ayusman
PY - 1992/12/1
Y1 - 1992/12/1
N2 - In aqueous medium, at 105-115 °C, SO4-. (generated from S2O82-) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.
AB - In aqueous medium, at 105-115 °C, SO4-. (generated from S2O82-) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.
UR - http://www.scopus.com/inward/record.url?scp=37049074627&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049074627&partnerID=8YFLogxK
U2 - 10.1039/C39920000892
DO - 10.1039/C39920000892
M3 - Article
AN - SCOPUS:37049074627
SN - 0022-4936
SP - 892
EP - 893
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 12
ER -