Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway

Minren Lin; Ayusman Sen

doi:10.1039/C39920000892

Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway

Minren Lin
, Ayusman Sen

Chemistry

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

In aqueous medium, at 105-115 °C, SO₄^-. (generated from S₂O₈^2-) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.

Original language	English (US)
Pages (from-to)	892-893
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39920000892
State	Published - Dec 1 1992

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39920000892

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title = "Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway",

abstract = "In aqueous medium, at 105-115 °C, SO4-. (generated from S2O82-) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.",

author = "Minren Lin and Ayusman Sen",

year = "1992",

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doi = "10.1039/C39920000892",

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pages = "892--893",

journal = "Journal of the Chemical Society D: Chemical Communications",

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}

Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway. / Lin, Minren; Sen, Ayusman.
In: Journal of the Chemical Society D: Chemical Communications, No. 12, 01.12.1992, p. 892-893.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway

AU - Lin, Minren

AU - Sen, Ayusman

PY - 1992/12/1

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N2 - In aqueous medium, at 105-115 °C, SO4-. (generated from S2O82-) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.

AB - In aqueous medium, at 105-115 °C, SO4-. (generated from S2O82-) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids.

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JF - Journal of the Chemical Society D: Chemical Communications

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ER -

Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. A model for alkane oxidation through the hydrogen-atom abstraction pathway

Abstract

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