OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE.

N. I. Kovtyukhova; V. M. Belousov; G. A. Konishevskaya; Yu N. Novikov; M. E. Vol'pin

OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE.

N. I. Kovtyukhova
, V. M. Belousov
, G. A. Konishevskaya
, Yu N. Novikov
, M. E. Vol'pin

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl//5 in cyclohexene solution in the temperature range 50-75 degree C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.

Original language	English (US)
Pages (from-to)	1158-1163
Number of pages	6
Journal	Kinetics and Catalysis
Volume	27
Issue number	6 pt 1
State	Published - Nov 1986

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Modeling and Simulation
Computer Science Applications

Cite this

@article{7fa71f9c84d649d0bd477d8bc6e6bd51,

title = "OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE.",

abstract = "The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl//5 in cyclohexene solution in the temperature range 50-75 degree C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.",

author = "Kovtyukhova, \{N. I.\} and Belousov, \{V. M.\} and Konishevskaya, \{G. A.\} and Novikov, \{Yu N.\} and Vol'pin, \{M. E.\}",

year = "1986",

month = nov,

language = "English (US)",

volume = "27",

pages = "1158--1163",

journal = "Kinetics and Catalysis",

issn = "0023-1584",

publisher = "Maik Nauka Publishing / Springer SBM",

number = "6 pt 1",

}

OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE. / Kovtyukhova, N. I.; Belousov, V. M.; Konishevskaya, G. A. et al.
In: Kinetics and Catalysis, Vol. 27, No. 6 pt 1, 11.1986, p. 1158-1163.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE.

AU - Kovtyukhova, N. I.

AU - Belousov, V. M.

AU - Konishevskaya, G. A.

AU - Novikov, Yu N.

AU - Vol'pin, M. E.

PY - 1986/11

Y1 - 1986/11

N2 - The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl//5 in cyclohexene solution in the temperature range 50-75 degree C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.

AB - The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl//5 in cyclohexene solution in the temperature range 50-75 degree C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.

UR - https://www.scopus.com/pages/publications/0022813759

UR - https://www.scopus.com/pages/publications/0022813759#tab=citedBy

M3 - Article

AN - SCOPUS:0022813759

SN - 0023-1584

VL - 27

SP - 1158

EP - 1163

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

IS - 6 pt 1

ER -

OXIDATION OF CYCLOHEXENE WITH OXYGEN CATALYZED BY A GRAPHITE INTERCALATION COMPOUND WITH MoCl//5. 1. KINETICS AND MECHANISM OF THE DECOMPOSITION OF CYCLOHEXENYL HYDROPEROXIDE.

Abstract

All Science Journal Classification (ASJC) codes

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