Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: A general, regiospecific synthesis of α-aryl ketones

Michael W. Justik; Gerald F. Koser

doi:10.1016/j.tetlet.2004.06.029

Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: A general, regiospecific synthesis of α-aryl ketones

Michael W. Justik
, Gerald F. Koser

School of Science (Behrend)

Research output: Contribution to journal › Article › peer-review

81 Scopus citations

Abstract

The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.

Original language	English (US)
Pages (from-to)	6159-6163
Number of pages	5
Journal	Tetrahedron Letters
Volume	45
Issue number	32
DOIs	https://doi.org/10.1016/j.tetlet.2004.06.029
State	Published - Aug 2 2004

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2004.06.029

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title = "Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95\% methanol: A general, regiospecific synthesis of α-aryl ketones",

abstract = "The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95\% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.",

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year = "2004",

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doi = "10.1016/j.tetlet.2004.06.029",

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T2 - A general, regiospecific synthesis of α-aryl ketones

AU - Justik, Michael W.

AU - Koser, Gerald F.

PY - 2004/8/2

Y1 - 2004/8/2

N2 - The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.

AB - The treatment of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol affords the corresponding α-aryl ketones. This oxidative rearrangement is general for acyclic and cyclic arylalkenes and permits regioselective syntheses of isomeric α-phenyl ketone pairs.

UR - https://www.scopus.com/pages/publications/3142740716

UR - https://www.scopus.com/pages/publications/3142740716#tab=citedBy

U2 - 10.1016/j.tetlet.2004.06.029

DO - 10.1016/j.tetlet.2004.06.029

M3 - Article

AN - SCOPUS:3142740716

SN - 0040-4039

VL - 45

SP - 6159

EP - 6163

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 32

ER -

Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: A general, regiospecific synthesis of α-aryl ketones

Abstract

All Science Journal Classification (ASJC) codes

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