TY - JOUR
T1 - Palladium-catalyzed asymmetric iodination of unactivated C-H bonds under mild conditions
AU - Giri, Ramesh
AU - Chen, Xiao
AU - Yu, Jin Quan
PY - 2005/3/29
Y1 - 2005/3/29
N2 - (Chemical Equation Presented) Specific, asymmetric, and mild: Oxazoline (Oxa), a removable chelating chiral auxiliary, assists in the asymmetric activation of C(sp3)-H bonds at the β position and C(sp 2)-H bonds at the γ position. Pd-(OAc)2 is an effective catalyst for the selective and asymmetric iodination of methyl, cyclopropyl, and aryl groups at room temperature (see formulae).
AB - (Chemical Equation Presented) Specific, asymmetric, and mild: Oxazoline (Oxa), a removable chelating chiral auxiliary, assists in the asymmetric activation of C(sp3)-H bonds at the β position and C(sp 2)-H bonds at the γ position. Pd-(OAc)2 is an effective catalyst for the selective and asymmetric iodination of methyl, cyclopropyl, and aryl groups at room temperature (see formulae).
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U2 - 10.1002/anie.200462884
DO - 10.1002/anie.200462884
M3 - Article
C2 - 15729724
AN - SCOPUS:17044366225
SN - 1433-7851
VL - 44
SP - 2112
EP - 2115
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 14
ER -