TY - JOUR
T1 - Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide
AU - Wojcinski, Louis M.
AU - Boyer, Michelle T.
AU - Sen, Ayusman
N1 - Funding Information:
This research was supported by a grant from the US Department of Energy, Office of Basic Energy Sciences (DE-FG02-84ER13295).
PY - 1998/4/2
Y1 - 1998/4/2
N2 - Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L2 = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene.
AB - Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L2 = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene.
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U2 - 10.1016/s0020-1693(97)05856-8
DO - 10.1016/s0020-1693(97)05856-8
M3 - Article
AN - SCOPUS:0038855504
SN - 0020-1693
VL - 270
SP - 8
EP - 11
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1-2
ER -