Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide

Louis M. Wojcinski; Michelle T. Boyer; Ayusman Sen

doi:10.1016/s0020-1693(97)05856-8

Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide

Louis M. Wojcinski
, Michelle T. Boyer
, Ayusman Sen

Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Cationic palladium(II) complexes of the type [L₂Pd(CH₃)(CH₃CN)]BF₄ (L₂ = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO₂ structure and an exclusive head-to-tail enchainment for propene.

Original language	English (US)
Pages (from-to)	8-11
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	270
Issue number	1-2
DOIs	https://doi.org/10.1016/s0020-1693(97)05856-8
State	Published - Apr 2 1998

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/s0020-1693(97)05856-8

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title = "Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide",

abstract = "Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L2 = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene.",

author = "Wojcinski, \{Louis M.\} and Boyer, \{Michelle T.\} and Ayusman Sen",

note = "Funding Information: This research was supported by a grant from the US Department of Energy, Office of Basic Energy Sciences (DE-FG02-84ER13295).",

year = "1998",

month = apr,

day = "2",

doi = "10.1016/s0020-1693(97)05856-8",

language = "English (US)",

volume = "270",

pages = "8--11",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide

AU - Wojcinski, Louis M.

AU - Boyer, Michelle T.

AU - Sen, Ayusman

N1 - Funding Information: This research was supported by a grant from the US Department of Energy, Office of Basic Energy Sciences (DE-FG02-84ER13295).

PY - 1998/4/2

Y1 - 1998/4/2

N2 - Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L2 = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene.

AB - Cationic palladium(II) complexes of the type [L2Pd(CH3)(CH3CN)]BF4 (L2 = 1,3-bis(diphenylphosphino)propane (Dppp) or 1,2-bis(2,5-dimethylphospholano)benzene (Me-Duphos)) were found to catalyze the alternating copolymerization of ethene, propene and cyclopentene with sulfur dioxide, as well as the terpolymerization of ethene, propene and sulfur dioxide. The resultant materials are high melting solids with an alternating alkene-SO2 structure and an exclusive head-to-tail enchainment for propene.

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U2 - 10.1016/s0020-1693(97)05856-8

DO - 10.1016/s0020-1693(97)05856-8

M3 - Article

AN - SCOPUS:0038855504

SN - 0020-1693

VL - 270

SP - 8

EP - 11

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

Palladium (II)-catalyzed alternating copolymerization of alkenes with sulfur dioxide

Abstract

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