TY - JOUR
T1 - Palladium(II)-catalyzed synthesis of polyamides (aramids) from aromatic dichlorides, diamines, and carbon monoxide
AU - Kim, Jang Sub
AU - Sen, Ayusman
N1 - Funding Information:
Funding for this research was provided by Akzo-Nobel, and the U.S. Department of Energy.
PY - 1999/7/8
Y1 - 1999/7/8
N2 - A novel catalytic procedure for the synthesis of polyamides (aramids) from aryl dichlorides, aryl diamines, and carbon monoxide has been developed. Palladium complexes incorporating bulky ligands, such as dippp (dippp = 1,3- bis(diisopropylphosphino)propane), are suitable catalysts for the reaction. Polyamides exhibiting inherent viscosity between 0.10 and 0.40 dl g-1 were obtained.
AB - A novel catalytic procedure for the synthesis of polyamides (aramids) from aryl dichlorides, aryl diamines, and carbon monoxide has been developed. Palladium complexes incorporating bulky ligands, such as dippp (dippp = 1,3- bis(diisopropylphosphino)propane), are suitable catalysts for the reaction. Polyamides exhibiting inherent viscosity between 0.10 and 0.40 dl g-1 were obtained.
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U2 - 10.1016/S1381-1169(98)00387-2
DO - 10.1016/S1381-1169(98)00387-2
M3 - Article
AN - SCOPUS:0001212358
SN - 1381-1169
VL - 143
SP - 197
EP - 201
JO - Journal of Molecular Catalysis A: Chemical
JF - Journal of Molecular Catalysis A: Chemical
IS - 1-3
ER -