Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

James H. Pawlow; Aaron D. Sadow; Ayusman Sen

doi:10.1021/om9707681

Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

James H. Pawlow, Aaron D. Sadow, Ayusman Sen

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Aliphatic polysuccinates in the molecular weight (M_w) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.

Original language	English (US)
Pages (from-to)	5659-5663
Number of pages	5
Journal	Organometallics
Volume	16
Issue number	26
DOIs	https://doi.org/10.1021/om9707681
State	Published - Dec 23 1997

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates",

abstract = "Aliphatic polysuccinates in the molecular weight (Mw) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.",

author = "Pawlow, {James H.} and Sadow, {Aaron D.} and Ayusman Sen",

year = "1997",

month = dec,

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doi = "10.1021/om9707681",

language = "English (US)",

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journal = "Organometallics",

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T1 - Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

AU - Pawlow, James H.

AU - Sadow, Aaron D.

AU - Sen, Ayusman

PY - 1997/12/23

Y1 - 1997/12/23

N2 - Aliphatic polysuccinates in the molecular weight (Mw) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.

AB - Aliphatic polysuccinates in the molecular weight (Mw) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.

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U2 - 10.1021/om9707681

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JF - Organometallics

IS - 26

ER -

Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

Abstract

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