Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

James H. Pawlow; Aaron D. Sadow; Ayusman Sen

doi:10.1021/om9707681

Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

James H. Pawlow
, Aaron D. Sadow
, Ayusman Sen

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Aliphatic polysuccinates in the molecular weight (M_w) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.

Original language	English (US)
Pages (from-to)	5659-5663
Number of pages	5
Journal	Organometallics
Volume	16
Issue number	26
DOIs	https://doi.org/10.1021/om9707681
State	Published - Dec 23 1997

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om9707681

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title = "Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates",

abstract = "Aliphatic polysuccinates in the molecular weight (Mw) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.",

author = "Pawlow, \{James H.\} and Sadow, \{Aaron D.\} and Ayusman Sen",

year = "1997",

month = dec,

day = "23",

doi = "10.1021/om9707681",

language = "English (US)",

volume = "16",

pages = "5659--5663",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

AU - Pawlow, James H.

AU - Sadow, Aaron D.

AU - Sen, Ayusman

PY - 1997/12/23

Y1 - 1997/12/23

N2 - Aliphatic polysuccinates in the molecular weight (Mw) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.

AB - Aliphatic polysuccinates in the molecular weight (Mw) range of 1,000-11,000 were produced from alkane-α,ω-dinitrites, alkene, and carbon monoxide using bis(benzonitrile)palladium-(II) chloride as a homogeneous catalyst. The alkane dinitrites may be synthesized from the corresponding aliphatic diols by reaction with either aqueous nitrous acid or nitrogen oxides. Nitric oxide, given off as a byproduct during polymerization, can be recycled to produce additional monomer.

UR - https://www.scopus.com/pages/publications/0013182090

UR - https://www.scopus.com/pages/publications/0013182090#tab=citedBy

U2 - 10.1021/om9707681

DO - 10.1021/om9707681

M3 - Article

AN - SCOPUS:0013182090

SN - 0276-7333

VL - 16

SP - 5659

EP - 5663

JO - Organometallics

JF - Organometallics

IS - 26

ER -

Palladium(II)-catalyzed terpolymerization of alkane-α,ω-dinitrite esters, alkenes, and carbon monoxide to polysuccinates

Abstract

All Science Journal Classification (ASJC) codes

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